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HEDH
A B C D E F G H I
Ideal gas: Ilexan, heat transfer medium, Illingworth, A, Imbedded fins, Immersed bodies: Immersed tubes, in fluidized beds, heat transfer to, Immiscible liquids, condensation of vapors producing Impairment of heat transfer in combined free and forced convection in a vertical pipe, Imperfectly diffuse surfaces: Impingement damage in heat exchangers, Impingement plate: Impingement protection, in shell-and-tube heat exchangers, Impinging jets: Implicit equations, solution of Inclined enclosures, free convective heat transfer in, Inclined flow, effect of on heat transfer to cylinders, Inclined pipes: Inclined surfaces, free convective heat transfer from, Inconel, spectral characteristics of reflectance from oxidized surface of, Induced flow instabilities, in augmentation of heat transfer, Injection: Inlet effects in shell-and-tube heat exchangers, In-line tube banks: Inorganic compounds, solutions of, as heat transfer media, Inorganic substances: Instability, parallel channel, in condensers, Insulators, thermal conductivity of, Integral condensation: Integral finned tubes: Interaction coefficients in heat exchangers, Interaction parameters for binary systems, tables, Interfacial friction, in three-phase (liquid-liquid-gas) stratified flows, Interfacial resistance, in condensation, Interfacial roughness, relationships for, in annular gas-liquid flow, Interfacial shear stress, effect on filmwise condensation, on vertical surface, Intergrannular corrosion, of Intermating troughs, as corrugation design in plate heat exchangers, Intermittent flows: Internal heat sources, temperature distribution in bodies with, Internal heat transfer coefficient, use in transient conduction calculations, Internal reboilers (in distillation columns), characteristics advantages and disadvantages of, Internally finned tubes: International codes for pressure vessels, Interpenetrating continua (as representation of heat exchangers): Intertube velocity, in tube banks, Inviscid flow, compressible, with heat addition, Iodine: Iodobenzene: Iodoethane: Iodomethane: ISO codes for mechanical design of heat exchangers, Isobutane: Isobutanol: Isobutylamine: Isobutylformate: Isobutyric acid: Isoparaffins: Isopentane: Isopentanol: Isopropanol: Isopropylacetate: Isopropylamine: Isopropylbenzene: Isopropylcyclohexane: Isothermal flow, compressible, in ducts, Isothermal gas, radiation heat transfer to walls from, Isotropic materials, elastic properties, Isotropic scattering, Italy, guide to national practice for heat exchanger mechanical design,
J K L M N O P Q R S T U V W X Y Z

Condensation of Vapour Mixtures Forming Immicible Liquids

DOI 10.1615/hedhme.a.000187

2.6 CONDENSATION
2.6.4 Condensation of vapour mixtures forming immiscible liquids

A. Introduction

The author would like to acknowledge the use he has made of the previous article in HEDH, written by R. Sardesai in 1983. However a significant change in approach has been adopted and the present article has been written as a consistent extension to Section 186. Section 186, Webb and McNaught (1980) and Webb (1990) should be read as pre-cursors to the present article.

The formation of a second immiscible condensate phase during condensation can affect the behaviour in a number of ways and reliable design should account for the possibility. Firstly various modes of condensation may occur. Thus it is possible for a single phase condensate to be formed. Vapours, which will form the other phase, act as non-condensing species imposing a greater gas-side resistance. Secondly when both liquid condensates are present the nature of the flow pattern will influence the condensate film heat transfer coefficient.

The various modes of heat transfer which are possible may be identified by consideration of the phase diagram, Figure 1, which applies for the case of mixtures which may be considered fully immiscible as liquids. The state of the mixture may lie in any of the four regions of the diagram, vapour, two-phase with liquid 1 present, two-phase with liquid 2 present or all liquid. Vapour-liquid equilibrium states with liquid 1 and 2 occur along FE and EG respectively, with the azeotrope at E, where vapour and both liquid phases co-exist at equilibrium.

Figure 1 Phase diagram for vapours which form immiscible condensates

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