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Baffle leakage in shell-and-tube heat exchangers: Baffles in shell-and-tube heat exchangers: Baker flow regime map for horizontal gas-liquid flow, Balance equation (applied to complete equipment), Band dryer: Bandel and Schlunder correlations, for boiling in horizontal tubes, Basket-type evaporator, Barbosa, J R Jr, Bateman, G, Bayonet tube heat exchangers, constructional features of, Bayonet tube evaporators, Beaton, C F, Beer-Lambert law, Bejan, A, Bell-Delaware method for shell-side heat transfer and pressure drop in shell-and-tube heat exchangers, Bell and Ghaly method for calculation of multicomponent condensation, Benard cells in free convection in horizontal fluid layers, Bends: Benzaldehyde: Benzene: Benzoic acid: Benzonitrile: Benzophenone: Benzyl alcohol: Benzyl chloride: Berenson equation for pool film boiling from a horizontal surface, Bergles, Arthur E, Bernoulli equation, application to flow across cylinders, Bimetallic tubes: Binary mixtures: Bingham fluid (non-Newtonian), Biofouling, Biot number: Biphenyl: Bismarck A, Black liquor, in pulp and paper industry, fouling of heat exchangers by, Black surface: Blackbody radiation, Blades, in scraped surface heat exchangers, Blake-Carmen-Kozeny equation, Blasius equation for friction factor, Blenkin, R, Blunt bodies, drag coefficients for, Boilers: Boiling: Boiling curve: Boiling length: Boiling number, definition, Boiling point, normal, Boiling range (in multicomponent mixtures): Boiling surface in boiling in vertical tubes, Boiling Water Reactor (BWR), fouling problems in, Bolted channel head in shell-and-tube exchanger, Bolted cone head in shell-and-tube heat exchanger, Bolted joints, thermal contact resistance in, Bolting, Bolting of flanges in shell-and-tube heat exchangers, Boltzmann's constant, Bonnet head, in shell-and-tube heat exchanger, Borishanski, V M, Borishanski correlation for nucleate pool boiling, Bott, T R, Boundary layer: Boussinesq approximations: Boussinesq number, definition, Bowring correlations for critical heat flux, Bracket supports for heat exchangers: Brauner, N, Brazed plate exchanger, Brazing in plate fin heat exchanger construction, Bricks, drying of, Brine recirculation, in multistage flash-evaporation, Brinkman number, Brittle fracture, Bromine: Bromley equation for film boiling from horizontal cylinders, Bromobenzene: Bromoethane: Bromomethane: Bromotrifluoromethane (Refrigerant 13B1): Brush and cage system, for fouling mitigation, BS 5500 code for mechanical design of shell-and-tube heat exchangers (see also PD 5500), Bubble crowding as mechanism of critical heat flux, Bubble flow: Bubbles: Bulk viscosity, Bundle-induced convection in kettle reboilers, Bundle layout, in condensers Buoyancy effects: Buoyancy-induced flow in channels, free convective heat transfer with, Busemann-Crocco integral, application in boundary layer equations, 1,2-Butadiene: 1,3-Butadiene: Butane: 1-Butanol: 2-Butanol: Butene-1: cis-2-Butene: trans-2-Butene: Butterworth, D, Butyl acetate: t-Butyl alcohol: Butylamine: Butylbenzene: n-Butylbenzene: n-Butylcyclohexane: Butylcyclopentane: Butylene oxide: Butyr-aldehyde: Butyric acid: Butyronitrile: Bypass (shell-and-tube bundle):
C D E F G H I J K L M N O P Q R S T U V W X Y Z

Condensation of Vapour Mixtures Forming Immicible Liquids

DOI 10.1615/hedhme.a.000187

2.6 CONDENSATION
2.6.4 Condensation of vapour mixtures forming immiscible liquids

A. Introduction

The author would like to acknowledge the use he has made of the previous article in HEDH, written by R. Sardesai in 1983. However a significant change in approach has been adopted and the present article has been written as a consistent extension to Section 186. Section 186, Webb and McNaught (1980) and Webb (1990) should be read as pre-cursors to the present article.

The formation of a second immiscible condensate phase during condensation can affect the behaviour in a number of ways and reliable design should account for the possibility. Firstly various modes of condensation may occur. Thus it is possible for a single phase condensate to be formed. Vapours, which will form the other phase, act as non-condensing species imposing a greater gas-side resistance. Secondly when both liquid condensates are present the nature of the flow pattern will influence the condensate film heat transfer coefficient.

The various modes of heat transfer which are possible may be identified by consideration of the phase diagram, Figure 1, which applies for the case of mixtures which may be considered fully immiscible as liquids. The state of the mixture may lie in any of the four regions of the diagram, vapour, two-phase with liquid 1 present, two-phase with liquid 2 present or all liquid. Vapour-liquid equilibrium states with liquid 1 and 2 occur along FE and EG respectively, with the azeotrope at E, where vapour and both liquid phases co-exist at equilibrium.

Figure 1 Phase diagram for vapours which form immiscible condensates

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