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Packaged units, specification of, Packing characteristic, in cooling towers, Packings, for cooling towers Packings, for fixed beds: Packinox heat exchanger, Paints, spectral characteristics of reflectance of surfaces treated with, Palen, J W Panchal, C B, Paraffins, normal and isonormal: Paraldehyde: Parallel channel instability, in condensers, Partial boiling in subcooled forced convective heat transfer, Participating media, radiation interaction in, Particle convective component, in heat transfer from fluidized beds, Particle emissivity, Particle Reynolds number in fixed beds, Particles: Particulate fluidization, Particulate fouling, Pass arrangements, in plate heat exchangers, Passes, tube side, Passive methods, for augmentation of heat transfer, passive systems for: PD5500 mechanical design of shell-and-tube heat exchangers to, Peacock, D K, Pearson number, Peclet number Peng-Robinson equation of state, application to hydrocarbons, Penner's rule, in absorption of radiation by gases,
Gas Radiation Properties
Pentachloroethane (Refrigerant 120): Pentadecane: Pentadecene: Pentadiene 1, 2: Pentadiene 1, trans 3: Pentadiene 1, 4: Pentadiene 2-3: Pentafluoroethane (Refrigerant 125) Pentamethylbenzene: Pentane: Pentanoic acid: 1-Pentanol: 1-Pentene: cis-2-Pentene: trans-2-Pentene: Pentylacetate: Pentylbenzene: Pentylcyclohexane: Pentylcyclopentane: Pentylcyclopropane, liquid properties, Perforated fins, in plate fin heat exchangers, Perforated plates, loss coefficients in, Periodic operation, of regenerator, Periodic variations in temperature, thermal conduction in bodies with, PFR correlation, for heat transfer in high fin tube banks, Pharmaceutical industry, fouling of heat exchangers in, Phase change materials, in augmentation of heat transfer, Phase change number, Phase equilibrium: Phase inversion Phase separation, as source of corrosion problems, Phenol: Phenols: Phenylhydrazine: Phonons, in thermal conductivity of solids, Phosgene: Physical properties: Pi theorum, in dimensional analysis, Pinch analysis, for heat exchanger network design, Pioro, I L Pioro, LS, Pipe leads, Piperidine: Pipes, circular: Pipes, noncircular: Piping components: Pitting corrosion, in stainless steels, Planck's constant, Planck's law, for spectral distribution of blackbody radiation, Plane shells, steady-state thermal conduction in, Plastic deformation Plate fin heat exchangers Plate fins, efficiency, Plate heat exchangers: Plate evaporator Plates: Plug flow: Plug flow model, for furnaces, Pneumatic conveyance, Pneumatic conveying dryer, P-NTU method: Polarization, of thermal radiation, Polyglycols, as heat transfer media, Polymers: Pool boiling, Porous surfaces: Port arrangements, in plate heat exchangers, Portable fouling unit, Poskas, P, Postdryout heat transfer: Powders: Power law fluid (non-Newtonian), Power plant: Prandtl number Precipitation (crystallization) fouling, Precipitation hardening, of stainless steels, Pressure coefficient: Pressure control of condensers, Pressure drop: Pressure gradient: Pressure, specification of in mechanical design to EN13445, Pressure testing, Pressure vessels, principle codes for, Pressurised water reactor, fouling in, Printed circuit heat exchanger, Problem table algorithm, in pinch analysis, Process heaters: Progressive plastic deformation Prolate spheroids, free convective heat transfer from, Promoters, in dropwise condensation, Propadiene: Propane: 1-Propanol: 2-Propanol: Propeller agitator, Property ratio method, for temperature dependent physical property Propionaldehyde: Propionic acid: Propionic anhydride: Proprionitrile: Propyl acetate: Propylamine: Propylbenzene: Propylcyclohexane: Propylcyclopentane: Propylene: 1,3-Propylene glycol: Propylene oxide: Propyl formate: Propyl propionate: Pseudo-boiling in supercritical fluids, Pseudo-film boiling in supercritical fluids, Pseudocritical pressure, Pseudocritical tempertaure, Pugh, S F Pulp and paper industry, fouling of heat exchangers in, Pulsations, use in augmentation of heat transfer, Pulverized fuel water-tube boiler, Pumping, lost work in, Pushkina and Sorokin correlation, for flooding in vertical tubes, Pyramid, free convective heat transfer from, Pyridine:

Index

HEDH
A B C D E F G H I J K L M N O P
Packaged units, specification of, Packing characteristic, in cooling towers, Packings, for cooling towers Packings, for fixed beds: Packinox heat exchanger, Paints, spectral characteristics of reflectance of surfaces treated with, Palen, J W Panchal, C B, Paraffins, normal and isonormal: Paraldehyde: Parallel channel instability, in condensers, Partial boiling in subcooled forced convective heat transfer, Participating media, radiation interaction in, Particle convective component, in heat transfer from fluidized beds, Particle emissivity, Particle Reynolds number in fixed beds, Particles: Particulate fluidization, Particulate fouling, Pass arrangements, in plate heat exchangers, Passes, tube side, Passive methods, for augmentation of heat transfer, passive systems for: PD5500 mechanical design of shell-and-tube heat exchangers to, Peacock, D K, Pearson number, Peclet number Peng-Robinson equation of state, application to hydrocarbons, Penner's rule, in absorption of radiation by gases,
Gas Radiation Properties
Pentachloroethane (Refrigerant 120): Pentadecane: Pentadecene: Pentadiene 1, 2: Pentadiene 1, trans 3: Pentadiene 1, 4: Pentadiene 2-3: Pentafluoroethane (Refrigerant 125) Pentamethylbenzene: Pentane: Pentanoic acid: 1-Pentanol: 1-Pentene: cis-2-Pentene: trans-2-Pentene: Pentylacetate: Pentylbenzene: Pentylcyclohexane: Pentylcyclopentane: Pentylcyclopropane, liquid properties, Perforated fins, in plate fin heat exchangers, Perforated plates, loss coefficients in, Periodic operation, of regenerator, Periodic variations in temperature, thermal conduction in bodies with, PFR correlation, for heat transfer in high fin tube banks, Pharmaceutical industry, fouling of heat exchangers in, Phase change materials, in augmentation of heat transfer, Phase change number, Phase equilibrium: Phase inversion Phase separation, as source of corrosion problems, Phenol: Phenols: Phenylhydrazine: Phonons, in thermal conductivity of solids, Phosgene: Physical properties: Pi theorum, in dimensional analysis, Pinch analysis, for heat exchanger network design, Pioro, I L Pioro, LS, Pipe leads, Piperidine: Pipes, circular: Pipes, noncircular: Piping components: Pitting corrosion, in stainless steels, Planck's constant, Planck's law, for spectral distribution of blackbody radiation, Plane shells, steady-state thermal conduction in, Plastic deformation Plate fin heat exchangers Plate fins, efficiency, Plate heat exchangers: Plate evaporator Plates: Plug flow: Plug flow model, for furnaces, Pneumatic conveyance, Pneumatic conveying dryer, P-NTU method: Polarization, of thermal radiation, Polyglycols, as heat transfer media, Polymers: Pool boiling, Porous surfaces: Port arrangements, in plate heat exchangers, Portable fouling unit, Poskas, P, Postdryout heat transfer: Powders: Power law fluid (non-Newtonian), Power plant: Prandtl number Precipitation (crystallization) fouling, Precipitation hardening, of stainless steels, Pressure coefficient: Pressure control of condensers, Pressure drop: Pressure gradient: Pressure, specification of in mechanical design to EN13445, Pressure testing, Pressure vessels, principle codes for, Pressurised water reactor, fouling in, Printed circuit heat exchanger, Problem table algorithm, in pinch analysis, Process heaters: Progressive plastic deformation Prolate spheroids, free convective heat transfer from, Promoters, in dropwise condensation, Propadiene: Propane: 1-Propanol: 2-Propanol: Propeller agitator, Property ratio method, for temperature dependent physical property Propionaldehyde: Propionic acid: Propionic anhydride: Proprionitrile: Propyl acetate: Propylamine: Propylbenzene: Propylcyclohexane: Propylcyclopentane: Propylene: 1,3-Propylene glycol: Propylene oxide: Propyl formate: Propyl propionate: Pseudo-boiling in supercritical fluids, Pseudo-film boiling in supercritical fluids, Pseudocritical pressure, Pseudocritical tempertaure, Pugh, S F Pulp and paper industry, fouling of heat exchangers in, Pulsations, use in augmentation of heat transfer, Pulverized fuel water-tube boiler, Pumping, lost work in, Pushkina and Sorokin correlation, for flooding in vertical tubes, Pyramid, free convective heat transfer from, Pyridine:
Q R S T U V W X Y Z
P Penner's rule, in absorption of radiation by gases,
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Gas Radiation Properties

DOI 10.1615/hedhme.a.000208

2.9 HEAT TRANSFER BY RADIATION
2.9.5 Gas radiation properties

D.K. Edwards

A. The equation of transfer

Up to this point, a diathermanous medium has been assumed. In such a medium the radiant intensity I of a stream of photons is unaffected by passage through the medium. More generally, the photons and matter interact. Three processes may be distinguished: (1) net absorption (total absorption minus induced emission), (2) spontaneous emission, and (3) scattering. The latter can be broken down into scattering out of the beam and scattering into the beam. The result is that in slant path increment ds there is an incremental change in intensity dI as pictured in Figure 1. The equation giving dI/ds is named the equation of transfer.

Figure 1 Change of intensity I along incremental path length ds

The absorption, emission, and scattering properties of matter are sometimes characterized by cross sections. For example, visualize a spherical oil droplet such as is sprayed into a combustion chamber. The droplet of radius R has a total surface area of 4πR2, but its projected area is πR2. The latter is said to be the geometric cross section. If one examines the shadow behind a droplet that is large compared to the wavelength, one finds, due to diffraction, a shadow area of 2πR2 but a bright halo contains half of the radiant power missing due to the shadow, half of I dΩ 2πR2. Whether the droplet is large or small, the radiant power missing from the incident beam divided by that incident on an area of πR2 is termed the extinction efficiency Qe. Thus if one considers the halo radiation as scattered, that is, caused to deviate in direction, the extinction efficiency of a large particle is 2; but, if one considers the halo as undeviated, a more reasonable view for engineering power transfer calculations, then Qe is 1 for a large particle.

The power missing from the shadow may have been absorbed, or it may have been scattered into other directions. The fraction scattered into other directions is called the albedo for single scatter ωs. The fraction 1 – ωs is sometimes called the particle emissivity. Actually it would be better called the particle absorptivity, but Kirchhoff’s law is invoked. The quantity ωsQe is called the scattering efficiency Qs, and (1 – ωs)Qe is called the absorption efficiency Qa.

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