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A B C D E F G H I J K L M N O P
Packaged units, specification of, Packing characteristic, in cooling towers, Packings, for cooling towers Packings, for fixed beds: Packinox heat exchanger, Paints, spectral characteristics of reflectance of surfaces treated with, Palen, J W Panchal, C B, Paraffins, normal and isonormal: Paraldehyde: Parallel channel instability, in condensers, Partial boiling in subcooled forced convective heat transfer, Participating media, radiation interaction in, Particle convective component, in heat transfer from fluidized beds, Particle emissivity, Particle Reynolds number in fixed beds, Particles: Particulate fluidization, Particulate fouling, Pass arrangements, in plate heat exchangers, Passes, tube side, Passive methods, for augmentation of heat transfer, passive systems for: PD5500 mechanical design of shell-and-tube heat exchangers to, Peacock, D K, Pearson number, Peclet number Peng-Robinson equation of state, application to hydrocarbons, Penner's rule, in absorption of radiation by gases, Pentachloroethane (Refrigerant 120): Pentadecane: Pentadecene: Pentadiene 1, 2: Pentadiene 1, trans 3: Pentadiene 1, 4: Pentadiene 2-3: Pentafluoroethane (Refrigerant 125) Pentamethylbenzene: Pentane: Pentanoic acid: 1-Pentanol: 1-Pentene: cis-2-Pentene: trans-2-Pentene: Pentylacetate: Pentylbenzene: Pentylcyclohexane: Pentylcyclopentane: Pentylcyclopropane, liquid properties, Perforated fins, in plate fin heat exchangers, Perforated plates, loss coefficients in, Periodic operation, of regenerator, Periodic variations in temperature, thermal conduction in bodies with, PFR correlation, for heat transfer in high fin tube banks, Pharmaceutical industry, fouling of heat exchangers in, Phase change materials, in augmentation of heat transfer, Phase change number, Phase equilibrium: Phase inversion Phase separation, as source of corrosion problems, Phenol: Phenols: Phenylhydrazine: Phonons, in thermal conductivity of solids, Phosgene: Physical properties: Pi theorum, in dimensional analysis, Pinch analysis, for heat exchanger network design, Pioro, I L Pioro, LS, Pipe leads, Piperidine: Pipes, circular: Pipes, noncircular: Piping components: Pitting corrosion, in stainless steels, Planck's constant, Planck's law, for spectral distribution of blackbody radiation, Plane shells, steady-state thermal conduction in, Plastic deformation Plate fin heat exchangers Plate fins, efficiency, Plate heat exchangers: Plate evaporator Plates: Plug flow: Plug flow model, for furnaces, Pneumatic conveyance, Pneumatic conveying dryer, P-NTU method: Polarization, of thermal radiation, Polyglycols, as heat transfer media, Polymers: Pool boiling, Porous surfaces: Port arrangements, in plate heat exchangers, Portable fouling unit, Poskas, P, Postdryout heat transfer: Powders: Power law fluid (non-Newtonian), Power plant: Prandtl number Precipitation (crystallization) fouling, Precipitation hardening, of stainless steels, Pressure coefficient: Pressure control of condensers, Pressure drop: Pressure gradient: Pressure, specification of in mechanical design to EN13445, Pressure testing, Pressure vessels, principle codes for, Pressurised water reactor, fouling in, Printed circuit heat exchanger, Problem table algorithm, in pinch analysis, Process heaters: Progressive plastic deformation Prolate spheroids, free convective heat transfer from, Promoters, in dropwise condensation, Propadiene: Propane: 1-Propanol: 2-Propanol: Propeller agitator, Property ratio method, for temperature dependent physical property Propionaldehyde: Propionic acid: Propionic anhydride: Proprionitrile: Propyl acetate: Propylamine: Propylbenzene: Propylcyclohexane: Propylcyclopentane: Propylene: 1,3-Propylene glycol: Propylene oxide: Propyl formate: Propyl propionate: Pseudo-boiling in supercritical fluids, Pseudo-film boiling in supercritical fluids, Pseudocritical pressure, Pseudocritical tempertaure, Pugh, S F Pulp and paper industry, fouling of heat exchangers in, Pulsations, use in augmentation of heat transfer, Pulverized fuel water-tube boiler, Pumping, lost work in, Pushkina and Sorokin correlation, for flooding in vertical tubes, Pyramid, free convective heat transfer from, Pyridine:
Q R S T U V W X Y Z

Introduction

DOI 10.1615/hedhme.a.000277

3.6.1 Introduction

A. General

One application of heat transfer equipment in the process industries is to supply vapors to distillation columns. These heat exchangers are called reboilers. Most process reboilers are of shell-and-tube construction. Boiling may take place either on the shell side (outside the tubes) or the tube side, depending on various requirements described in the next section. The heating medium is usually steam, but it may also be a heat transfer service fluid or a gas, condensing vapor, or liquid process stream.

The rate of vaporization in a reboiler is sensitive to the available temperature difference because the boiling heat transfer coefficient itself is a strong function of the temperature difference. In cases where adequate ΔT is available, gross approximations in design are often made without serious consequence because vaporization can easily be adjusted to the required level by adjusting ΔT. However, continuing trends toward more efficient energy utilization tend to permit less flexibility in heating medium operating conditions. This produces a requirement for better reboiler selection, much more accurate sizing of heat transfer surface, and better analysis and prediction of probable performance. Furthermore, even with adequate ΔT available, reboiler performance is always limited by a "critical heat flux" above which vapor blanketing takes place.

Because of the complicated nature of the boiling process, very complex calculations are required for a comprehensive design, and use of computers has become standard practice, at least for the more critical designs. The boiling heat transfer coefficient decreases sharply with decreasing ΔT. Therefore, the trend towards smaller ΔT has prompted the use and further study of various types of enhanced boiling surfaces that provide more surface and/or more bubble nucleation sites at low \(\varDelta T.\) Use of some of these surfaces is described in later sections.

One of the great unknowns in the use of enhanced surfaces and in reboiler design is the effect of fouling. Because of the usually high values of the heat transfer coefficients in reboilers, the fouling resistance assigned can represent a large part of the required heat transfer surface. However, it has been frequent practice in the past to specify high fouling factors to make up for gross simplifications in the analysis of the boiling process. Actually, many process reboilers will operate with a very small amount of fouling if properly designed (e.g., see Gilmour, 1965), and the assigned fouling factor is often just a "safety" factor. Sometimes what was thought to be fouling was actually a failure to take into account the effects of wide-boiling mixtures on the heat transfer coefficient. Another possible cause of poor performance that at first appears to be fouling is the build-up of heavy components due to insufficient liquid flow out of the reboilers. This causes a gradual increase in boiling temperature with corresponding decreases in ΔT and performance. When extremely large fouling factors actually are required it is often a sign that the designer should investigate other geometries, higher velocities, or lower wall temperatures.

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