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Baffle leakage in shell-and-tube heat exchangers: Baffles in shell-and-tube heat exchangers: Baker flow regime map for horizontal gas-liquid flow, Balance equation (applied to complete equipment), Band dryer: Bandel and Schlunder correlations, for boiling in horizontal tubes, Basket-type evaporator, Barbosa, J R Jr, Bateman, G, Bayonet tube heat exchangers, constructional features of, Bayonet tube evaporators, Beaton, C F, Beer-Lambert law, Bejan, A, Bell-Delaware method for shell-side heat transfer and pressure drop in shell-and-tube heat exchangers, Bell and Ghaly method for calculation of multicomponent condensation, Benard cells in free convection in horizontal fluid layers, Bends: Benzaldehyde: Benzene: Benzoic acid: Benzonitrile: Benzophenone: Benzyl alcohol: Benzyl chloride: Berenson equation for pool film boiling from a horizontal surface, Bergles, Arthur E, Bernoulli equation, application to flow across cylinders, Bimetallic tubes: Binary mixtures: Bingham fluid (non-Newtonian), Biofouling, Biot number: Biphenyl: Bismarck A, Black liquor, in pulp and paper industry, fouling of heat exchangers by, Black surface: Blackbody radiation, Blades, in scraped surface heat exchangers, Blake-Carmen-Kozeny equation, Blasius equation for friction factor, Blenkin, R, Blunt bodies, drag coefficients for, Boilers: Boiling: Boiling curve: Boiling length: Boiling number, definition, Boiling point, normal, Boiling range (in multicomponent mixtures): Boiling surface in boiling in vertical tubes, Boiling Water Reactor (BWR), fouling problems in, Bolted channel head in shell-and-tube exchanger, Bolted cone head in shell-and-tube heat exchanger, Bolted joints, thermal contact resistance in, Bolting, Bolting of flanges in shell-and-tube heat exchangers, Boltzmann's constant, Bonnet head, in shell-and-tube heat exchanger, Borishanski, V M, Borishanski correlation for nucleate pool boiling, Bott, T R, Boundary layer: Boussinesq approximations: Boussinesq number, definition, Bowring correlations for critical heat flux, Bracket supports for heat exchangers: Brauner, N, Brazed plate exchanger, Brazing in plate fin heat exchanger construction, Bricks, drying of, Brine recirculation, in multistage flash-evaporation, Brinkman number, Brittle fracture, Bromine: Bromley equation for film boiling from horizontal cylinders, Bromobenzene: Bromoethane: Bromomethane: Bromotrifluoromethane (Refrigerant 13B1): Brush and cage system, for fouling mitigation, BS 5500 code for mechanical design of shell-and-tube heat exchangers (see also PD 5500), Bubble crowding as mechanism of critical heat flux, Bubble flow: Bubbles: Bulk viscosity, Bundle-induced convection in kettle reboilers, Bundle layout, in condensers Buoyancy effects: Buoyancy-induced flow in channels, free convective heat transfer with, Busemann-Crocco integral, application in boundary layer equations, 1,2-Butadiene: 1,3-Butadiene: Butane: 1-Butanol: 2-Butanol: Butene-1: cis-2-Butene: trans-2-Butene: Butterworth, D, Butyl acetate: t-Butyl alcohol: Butylamine: Butylbenzene: n-Butylbenzene: n-Butylcyclohexane: Butylcyclopentane: Butylene oxide: Butyr-aldehyde: Butyric acid: Butyronitrile: Bypass (shell-and-tube bundle):

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Baffle leakage in shell-and-tube heat exchangers: Baffles in shell-and-tube heat exchangers: Baker flow regime map for horizontal gas-liquid flow, Balance equation (applied to complete equipment), Band dryer: Bandel and Schlunder correlations, for boiling in horizontal tubes, Basket-type evaporator, Barbosa, J R Jr, Bateman, G, Bayonet tube heat exchangers, constructional features of, Bayonet tube evaporators, Beaton, C F, Beer-Lambert law, Bejan, A, Bell-Delaware method for shell-side heat transfer and pressure drop in shell-and-tube heat exchangers, Bell and Ghaly method for calculation of multicomponent condensation, Benard cells in free convection in horizontal fluid layers, Bends: Benzaldehyde: Benzene: Benzoic acid: Benzonitrile: Benzophenone: Benzyl alcohol: Benzyl chloride: Berenson equation for pool film boiling from a horizontal surface, Bergles, Arthur E, Bernoulli equation, application to flow across cylinders, Bimetallic tubes: Binary mixtures: Bingham fluid (non-Newtonian), Biofouling, Biot number: Biphenyl: Bismarck A, Black liquor, in pulp and paper industry, fouling of heat exchangers by, Black surface: Blackbody radiation, Blades, in scraped surface heat exchangers, Blake-Carmen-Kozeny equation, Blasius equation for friction factor, Blenkin, R, Blunt bodies, drag coefficients for, Boilers: Boiling: Boiling curve: Boiling length: Boiling number, definition, Boiling point, normal, Boiling range (in multicomponent mixtures): Boiling surface in boiling in vertical tubes, Boiling Water Reactor (BWR), fouling problems in, Bolted channel head in shell-and-tube exchanger, Bolted cone head in shell-and-tube heat exchanger, Bolted joints, thermal contact resistance in, Bolting, Bolting of flanges in shell-and-tube heat exchangers, Boltzmann's constant, Bonnet head, in shell-and-tube heat exchanger, Borishanski, V M, Borishanski correlation for nucleate pool boiling, Bott, T R, Boundary layer: Boussinesq approximations: Boussinesq number, definition, Bowring correlations for critical heat flux, Bracket supports for heat exchangers: Brauner, N, Brazed plate exchanger, Brazing in plate fin heat exchanger construction, Bricks, drying of, Brine recirculation, in multistage flash-evaporation, Brinkman number, Brittle fracture, Bromine: Bromley equation for film boiling from horizontal cylinders, Bromobenzene: Bromoethane: Bromomethane: Bromotrifluoromethane (Refrigerant 13B1): Brush and cage system, for fouling mitigation, BS 5500 code for mechanical design of shell-and-tube heat exchangers (see also PD 5500), Bubble crowding as mechanism of critical heat flux, Bubble flow: Bubbles: Bulk viscosity, Bundle-induced convection in kettle reboilers, Bundle layout, in condensers Buoyancy effects: Buoyancy-induced flow in channels, free convective heat transfer with, Busemann-Crocco integral, application in boundary layer equations, 1,2-Butadiene: 1,3-Butadiene: Butane: 1-Butanol: 2-Butanol: Butene-1: cis-2-Butene: trans-2-Butene: Butterworth, D, Butyl acetate: t-Butyl alcohol: Butylamine: Butylbenzene: n-Butylbenzene: n-Butylcyclohexane: Butylcyclopentane: Butylene oxide: Butyr-aldehyde: Butyric acid: Butyronitrile: Bypass (shell-and-tube bundle):
C D E F G H I J K L M N O P Q R S T U V W X Y Z

Vapour Pressure, Enthalpies of Vaporisation and Boiling and Melting Points of Pure Fluids

DOI 10.1615/hedhme.a.000500

5.1 PROPERTIES OF PURE FLUIDS
5.1.3 Vapour pressures, enthalpies of vaporisation and boiling and melting points of pure fluids

A. Introduction

In this section we examine how to estimate vapour pressures, enthalpies of vaporisation and boiling and melting temperatures of pure fluids. These properties play an important role in the design and operation of many chemical and physical processes.

B. Vapour pressure

The work of Boublik et al. (1984) constitutes an excellent source of experimental data for more than 1,000 substances. Data are usually correlated as a function of temperature using either the Antoine equation or the more accurate Wagner equation. The Antoine equation is obtained from the Clapeyron equation and should only be used over the range of temperatures over which the coefficients A, B, and C have been determined. It is usually presented as:

\[\label{eq1} \ln(p/p^0)=A-\dfrac{B}{T+C}\,. \tag{1}\]

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