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Lamella heat exchangers, Laminar flow: Laminar flow control, of boundary layers, Lancaster, J F, Langelier index for water quality, Large eddy simulation, in prediction of turbulent boundary layers, Laws for turbulent flows: Layers of fluid, free convection heat transfer in, Le Fevre equations for free convective heat transfer, Leakage between streams, in shell-and-tube heat exchangers Leakage effects, on heat transfer and pressure drop in shell-and-tube heat exchangers, Leaks, in heat exchanger, sealing by explosive welding, Lebedev, M E, Lee and Kesler equation, for vapour pressure, L-footed fins, Lessing rings, characteristic of, as packings for fixed beds, Li equation, for critical temperature of mixtures, Lienhard and Dhir analysis of critical heat flux in pool boiling, Lienhard and Eichhorn criterion, for transition in critical heat flux mechanism in crossflow over single tube, Lift force: Liley, P E, Limb, D, Limpet coils: Linnhoff, B, Liquefaction, exergy analysis of, Liquid fluidized beds, Liquid fuels, properties of, Liquid hold-up, Liquid-liquid-gas flow, Liquid-liquid flow, Liquid metals: Liquid sheets, in direct contact heat transfer, Liquid-solid interfaces, fouling at, Liquids: Lister, D H, Local conditions hypothesis, for critical heat flux in flow boiling, Lockhart and Martinelli correlations: Lodge's rubberlike liquid (non-Newtonian), Logarithmic law region, Logarithmic mean temperature difference Longitudinal flow and heat transfer in tube banks, Long-tube vertical evaporator, Loss coefficient, Lost work in unit operations/exergy analysis, Louvered fins, in plate fin exchangers, Low-alloy steels: Low-finned tubes: Low-nickel steels, Lubricants, physical properties: Lucas methods
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Vapour Pressure, Enthalpies of Vaporisation and Boiling and Melting Points of Pure Fluids

DOI 10.1615/hedhme.a.000500

5.1 PROPERTIES OF PURE FLUIDS
5.1.3 Vapour pressures, enthalpies of vaporisation and boiling and melting points of pure fluids

A. Introduction

In this section we examine how to estimate vapour pressures, enthalpies of vaporisation and boiling and melting temperatures of pure fluids. These properties play an important role in the design and operation of many chemical and physical processes.

B. Vapour pressure

The work of Boublik et al. (1984) constitutes an excellent source of experimental data for more than 1,000 substances. Data are usually correlated as a function of temperature using either the Antoine equation or the more accurate Wagner equation. The Antoine equation is obtained from the Clapeyron equation and should only be used over the range of temperatures over which the coefficients A, B, and C have been determined. It is usually presented as:

\[\label{eq1} \ln(p/p^0)=A-\dfrac{B}{T+C}\,. \tag{1}\]

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