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A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
Rabas and Taborek correlation, for heat transfer in banks of low fin tubes, Rackett equation (modified) for liquid density
for pure liquids, for liquid mixtures,
Phase Behaviour of Mixtures
Radiation: Radiation shields, in radiation heat transfer, Radiation source analysis, Radiative heat transfer: Radiators, automotive, construction, Radiometers, application in gas radiation property measurement, Radiosity, Stephan's law for, Radiosity-irradiation formulations in radiative heat transfer, Rankine cycle in refrigeration, Rao, B K Raoult's law for partial pressure, Rating of heat exchangers, Rayleigh instability, in free convection, Rayleigh number Reay, D Reboilers: Reciprocal mode integrating sphere, for reflection and transmission measurements in radiation, Rectangles: Rectangular ducts: Rectangular enclosures, free convective heat transfer in: Rectangular fins, for plate fin exchangers Reduced pressure, correlations for pool boiling using, Reference temperature: Refinery processes, fouling in, Reflection, of thermal radiation, from solid surfaces: Reflectivity, of solid surfaces, Reflectometer, heated cavity, Reflux condensers, Refractories, density of, Refractory surfaces, Refrigerants: Refrigerant 11 (Trichlorofluoromethane): Refrigerant 12 (Dichlorodifluoromethane): Refrigerant 13 (Chlorotrifluoromethane): Refrigerant 21 (Dichlorofluoromethane): Refrigerant 22 (Chlorodifluoromethane): Refrigerant 116: Refrigerant plant, entropy generation in, Refrigeration, heat transfer in, Regenerators and thermal energy storage, Regimes of heat transfer, in ducts, single phase flow, Reidel method, for predicting enthalpy of vaporisation, Reinforcing rings, for expansion bellows, Relaminarization, of turbulent flow, Reichenberg method, for effect of pressure on gas viscosity, Relief system design for shell-and-tube heat exchangers with tube side failure, Removal of fouling deposits: Renewable fuels, properties of, Renotherm, heat transfer medium, Repair, of expansion bellows, Residence times, in dryers: Resistance network analysis, Resistance (thermal) due to fouling: Reversible (minimum) work, in Reynolds number, Reynolds stress models, for turbulence, Rheologically complex materials, properties of: Rheological properties of drag reducing agents Rheology, shear flow experiments used in, Rhine, J M, Ribatski, G, Riblets for drag reduction, Richardson number, Richie, J M, Ring cells, in free convection, RODbaffles, in tube bundles with longitudinal flow, Rod bundles: Rohsenow correlation, for nucleate boiling, Roll cells, in free convection, Roller expansion, of tubes into tube sheets, Rose, J W, Rossby number, Rotary dryer, Rotating drums, heat transfer to particle bed in, Rotating surface, in an annular duct Rotation, as device for heat transfer augmentation, Roughness, surface: Rough walled passages, radiative heat transfer down, Rubber (sponge) balls, in fouling mitigation, Ryznar index for water quality,

Index

HEDH
A B C D E F G H I J K L M N O P Q R
Rabas and Taborek correlation, for heat transfer in banks of low fin tubes, Rackett equation (modified) for liquid density
for pure liquids, for liquid mixtures,
Phase Behaviour of Mixtures
Radiation: Radiation shields, in radiation heat transfer, Radiation source analysis, Radiative heat transfer: Radiators, automotive, construction, Radiometers, application in gas radiation property measurement, Radiosity, Stephan's law for, Radiosity-irradiation formulations in radiative heat transfer, Rankine cycle in refrigeration, Rao, B K Raoult's law for partial pressure, Rating of heat exchangers, Rayleigh instability, in free convection, Rayleigh number Reay, D Reboilers: Reciprocal mode integrating sphere, for reflection and transmission measurements in radiation, Rectangles: Rectangular ducts: Rectangular enclosures, free convective heat transfer in: Rectangular fins, for plate fin exchangers Reduced pressure, correlations for pool boiling using, Reference temperature: Refinery processes, fouling in, Reflection, of thermal radiation, from solid surfaces: Reflectivity, of solid surfaces, Reflectometer, heated cavity, Reflux condensers, Refractories, density of, Refractory surfaces, Refrigerants: Refrigerant 11 (Trichlorofluoromethane): Refrigerant 12 (Dichlorodifluoromethane): Refrigerant 13 (Chlorotrifluoromethane): Refrigerant 21 (Dichlorofluoromethane): Refrigerant 22 (Chlorodifluoromethane): Refrigerant 116: Refrigerant plant, entropy generation in, Refrigeration, heat transfer in, Regenerators and thermal energy storage, Regimes of heat transfer, in ducts, single phase flow, Reidel method, for predicting enthalpy of vaporisation, Reinforcing rings, for expansion bellows, Relaminarization, of turbulent flow, Reichenberg method, for effect of pressure on gas viscosity, Relief system design for shell-and-tube heat exchangers with tube side failure, Removal of fouling deposits: Renewable fuels, properties of, Renotherm, heat transfer medium, Repair, of expansion bellows, Residence times, in dryers: Resistance network analysis, Resistance (thermal) due to fouling: Reversible (minimum) work, in Reynolds number, Reynolds stress models, for turbulence, Rheologically complex materials, properties of: Rheological properties of drag reducing agents Rheology, shear flow experiments used in, Rhine, J M, Ribatski, G, Riblets for drag reduction, Richardson number, Richie, J M, Ring cells, in free convection, RODbaffles, in tube bundles with longitudinal flow, Rod bundles: Rohsenow correlation, for nucleate boiling, Roll cells, in free convection, Roller expansion, of tubes into tube sheets, Rose, J W, Rossby number, Rotary dryer, Rotating drums, heat transfer to particle bed in, Rotating surface, in an annular duct Rotation, as device for heat transfer augmentation, Roughness, surface: Rough walled passages, radiative heat transfer down, Rubber (sponge) balls, in fouling mitigation, Ryznar index for water quality,
S T U V W X Y Z
R Rackett equation (modified) for liquid density for liquid mixtures,
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Phase Behaviour of Mixtures

DOI 10.1615/hedhme.a.000503

5.2 PROPERTIES OF MIXTURES OF FLUIDS
5.2.1. Density of fluid mixtures

A. Fenghour

A. Introduction

Practical methods for the calculation of the density of gas and liquid mixtures as a function of temperature and pressure are presented in this section. The methods are illustrated with worked examples and the results compared with experimental data. Methods based on the corresponding states principle are quite accurate and can be used up to high pressure, of the order of several hundred bar. The virial approach is accurate at low pressures but its performance worsens with increasing pressure and is not recommended above about 50 bar. For saturated liquid mixtures the correlations proposed by Hankinson and Thomson (1979) and Spencer and Danner (1973) are recommended. For compressed liquid mixtures the method of Thomson et al. (1982) is quite accurate. Only methods which are easy to implement have been selected. More elaborate thermodynamic models such as equations of state, which in principle allow the calculation of all the thermodynamic properties of single substances or mixtures, are beyond the scope of this article because their implementation would require the development of computer programs with lengthy testing periods. Wherever possible guidelines on the accuracy of the recommended methods are provided.

B. Gas mixtures

(a) Corresponding states principle

In the application of the corresponding states principle to mixtures it is necessary first to determine the pseudocritical parameters of the mixture of interest. In Section 508 it is shown how to estimate these scaling parameters through a process of averaging of the constants of the pure constituent components. Once the pseudocritical parameters of a given mixture have been determined, the procedure outlined in Section 499B can be used. This procedure treats the mixture as a fictitious substance, or pseudo-component, when its compression factor Zm(Tr,pr) at reduced conditions of temperature and pressure is given by the following three-parameter correlation (Pitzer et al., 1955):

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