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A B C D E F G H I J K L M N O P Q R S
Saddle supports, for heat exchangers, Safety factors, Safety, of heat exchangers: Salicyl aldehyde: Salts, heat transfer, as heat transfer media, Sand roughness, equivalent, Santotherm, heat transfer media, Sastri and Rao correlation for surface tension, Saturated boiling: Saturated density: Saturated fluids, tables of physical properties, Saturation pressure, Saturation temperature, Saunders, E A D Sauer, H J Jr, Scale formation in heat exchangers, Scaling approximations, in nonisothermal gas radiation, Scattering bed models, for radiative heat transfer from surfaces, Scattering, interaction phenomena with, Scattering coefficient, Schack wide-band model, for gas radiation properties, Schick and Prausnitz method, for critical volume of mixtures, Schlunder, E U Schmidt, F W Schmidt correlation, for heat transfer in in-line banks of high fin tubes, Schmidt number, Schneider, G E, Schrock and Grossman correlations, for forced convective heat transfer in two-phase flow, Schunk, M Schwier, K, Scraped surfaces: Scaling devices, in shell-and-tube heat exchangers, Seawater physical properties, Seider-Tate equation, for heat transfer in heat exchangers, Selection of heat transfer equipment: Semiconductors, thermal conductivity, Separated flow model: Separation, exergy analysis for, Separators, for use in association with evaporators, Series solutions, for one-dimensional transient conduction, Serrated fins, in plate fin heat exchangers, Shah correlation for boiling, Shah correlation, for boiling in horizontal tubes, Shape factor, in radiative heat transfer between diffuse surfaces, Shear flow, of non-Newtonian fluids, Shear free flow, of non-Newtonian fluids, Shear rate, in fluid, Shear stress: Sheffield, J W, Shelf dryer, Shell-and-tube heat exchanger: Shell-to-baffle clearance, in shell-and-tube heat exchangers, Shells, for shell-and-tube heat exchangers: Sherwood number Shipes, K V, Short-tube vertical evaporator, Sigma phase embrittlement, of stainless steels, Silicate scales, in heat exchangers, Silicone oils, as heat transfer media, physical properties of, Silver method, for calculation of multicomponent condensation, Similarity theory, Simonis, V, Single-phase fluid flow: Single stage flash evaporation (SSF): Singularities, two-phase gas-liquid pressure drop across, Sink, in radiation: Skid-mounted units, specification of, Skin friction coefficient, Skrinska, A, Slab: Sleeves, internal, for expansion bellows, Slot: Slug flow: Slugging, in fluidized beds, Smith, A A, Smith, R, Smith, R A Smith, O, Snell's law, in radiation, Software, for code design, Solar absorber, Solar reflector, Soldered fins, in double pipe exchangers, Solid fuels, properties of, Solids circulation, in fluidized beds, Solid-gas flow: Solid-liquid flow: Solidification: Solids: Solids circulation, in fluidized beds, Soot blowing, Sound velocity: Source, in radiation: Spacers, in shell-and-tube heat exchangers, Spalding, D B, Sparging: Specific enthalpy, Specific entropy: Specific heat capacity, Specific internal energy, Specific volume: Specification of heat exchangers, Spectral absorptivity: Spectral emissivity, in gases, Specular surface, Specular-walled passages, radiative heat transfer in, Spheres: Spherical coordinates, for finite difference equations for conduction, Spherical shells: Spheroids (oblate and prolate), free convective heat transfer from, Spine fins: Spiral heat exchanger: Spirally fluted tubes: Sponge rubber balls, in fouling mitigation, Spray dryers, Sprays, in heat exchangers, Square ducts: Stable equilibrium, of vapor and liquid, Staggered tube banks: Stainless steels, Stanton number Startup: State diagram, for fluidized beds, Static mixers, in heat exchangers, Statically stable foams, Steam, dropwise condensation of, Steam tables, Steam turbine exhaust condensers, Steels, as material of construction, Stefan-Boltzmann constant, Stefan's law, for blackbody radiation, Stegmaier, W, Steiner and Taborek correlation, for forced convective boiling, Stephan and Korner correlation, for boiling of binary mixtures, Stiffeners, PD5500 code guidelines for, Stiffeners, against external pressure, EN13445 guidance on, Stirred beds, heat transfer to, Stirred reactor model, for furnaces, Stone's strongly implicit method, Straight fins (longitudinal fins): Stratified gas-liquid flow: Stratified liquid-liquid-gas flow: Steam analysis methods, for shell-side heat transfer and pressure drop in shell-and-tube heat exchangers, Stress, compressive, in heat exchanger tubes, Stress corrosion cracking, of stainless steels, Stress equation models, for turbulent boundary layers, Stress-strain curve, for solids, Stress tensor: Stresses: Strip baffles, in tube bundles with longitudinal flow, Strouhal number, Subchannel analysis, for critical heat flux in rod bundles, Subcooled boiling: Subcooling: Sublayer, viscous, Submerged combustion, Successive over-under relaxation method for solution of implicit equations, Suction: Suction line exchangers in refrigeration, Sulfur: Sulfur compounds (organic): Sulfur dioxide: Sulfur hexafluoride: Sulfur trioxide: Supercritical fluids: Superficial velocity, in multiphase flow, Superheated gases: Superheated liquid, in metastable state, Superheated vapor, condensation of, on vertical surface, Supersaturation, as cause of fogging in condensers: Suppression of nucleate boiling, Surface catalysis, in augmentation of heat transfer, Surface condensers, Surface finish: Surface, hydraulically smooth, Surface material, effect on fouling, Surface models, in radiative heat transfer, Surface modification for drag reduction, Surface temperature, effect on fouling, Surface tension: Surfactants, in drag reduction, Suspension, radiation interaction phenomena in, Sutherland formula, for viscosity variation with temperature, Sutterby fluid (non-Newtonian), free convective heat transfer to, Swirling flow, in augmentation of heat transfer, Synthetic heat transfer media, Synthetic mixture heat transfer media,
T U V W X Y Z

Phase Behaviour of Mixtures

DOI 10.1615/hedhme.a.000503

5.2 PROPERTIES OF MIXTURES OF FLUIDS
5.2.1. Density of fluid mixtures

A. Introduction

Practical methods for the calculation of the density of gas and liquid mixtures as a function of temperature and pressure are presented in this section. The methods are illustrated with worked examples and the results compared with experimental data. Methods based on the corresponding states principle are quite accurate and can be used up to high pressure, of the order of several hundred bar. The virial approach is accurate at low pressures but its performance worsens with increasing pressure and is not recommended above about 50 bar. For saturated liquid mixtures the correlations proposed by Hankinson and Thomson (1979) and Spencer and Danner (1973) are recommended. For compressed liquid mixtures the method of Thomson et al. (1982) is quite accurate. Only methods which are easy to implement have been selected. More elaborate thermodynamic models such as equations of state, which in principle allow the calculation of all the thermodynamic properties of single substances or mixtures, are beyond the scope of this article because their implementation would require the development of computer programs with lengthy testing periods. Wherever possible guidelines on the accuracy of the recommended methods are provided.

B. Gas mixtures

(a) Corresponding states principle

In the application of the corresponding states principle to mixtures it is necessary first to determine the pseudocritical parameters of the mixture of interest. In Section 508 it is shown how to estimate these scaling parameters through a process of averaging of the constants of the pure constituent components. Once the pseudocritical parameters of a given mixture have been determined, the procedure outlined in Section 499B can be used. This procedure treats the mixture as a fictitious substance, or pseudo-component, when its compression factor Zm(Tr,pr) at reduced conditions of temperature and pressure is given by the following three-parameter correlation (Pitzer et al., 1955):

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