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Rabas and Taborek correlation, for heat transfer in banks of low fin tubes, Rackett equation (modified) for liquid density Radiation: Radiation shields, in radiation heat transfer, Radiation source analysis, Radiative heat transfer: Radiators, automotive, construction, Radiometers, application in gas radiation property measurement, Radiosity, Stephan's law for, Radiosity-irradiation formulations in radiative heat transfer, Rankine cycle in refrigeration, Rao, B K Raoult's law for partial pressure, Rating of heat exchangers, Rayleigh instability, in free convection, Rayleigh number Reay, D Reboilers: Reciprocal mode integrating sphere, for reflection and transmission measurements in radiation, Rectangles: Rectangular ducts: Rectangular enclosures, free convective heat transfer in: Rectangular fins, for plate fin exchangers Reduced pressure, correlations for pool boiling using, Reference temperature: Refinery processes, fouling in, Reflection, of thermal radiation, from solid surfaces: Reflectivity, of solid surfaces, Reflectometer, heated cavity, Reflux condensers, Refractories, density of, Refractory surfaces, Refrigerants: Refrigerant 11 (Trichlorofluoromethane): Refrigerant 12 (Dichlorodifluoromethane): Refrigerant 13 (Chlorotrifluoromethane): Refrigerant 21 (Dichlorofluoromethane): Refrigerant 22 (Chlorodifluoromethane): Refrigerant 116: Refrigerant plant, entropy generation in, Refrigeration, heat transfer in, Regenerators and thermal energy storage, Regimes of heat transfer, in ducts, single phase flow, Reidel method, for predicting enthalpy of vaporisation, Reinforcing rings, for expansion bellows, Relaminarization, of turbulent flow, Reichenberg method, for effect of pressure on gas viscosity, Relief system design for shell-and-tube heat exchangers with tube side failure, Removal of fouling deposits: Renewable fuels, properties of, Renotherm, heat transfer medium, Repair, of expansion bellows, Residence times, in dryers: Resistance network analysis, Resistance (thermal) due to fouling: Reversible (minimum) work, in Reynolds number, Reynolds stress models, for turbulence, Rheologically complex materials, properties of: Rheological properties of drag reducing agents Rheology, shear flow experiments used in, Rhine, J M, Ribatski, G, Riblets for drag reduction, Richardson number, Richie, J M, Ring cells, in free convection, RODbaffles, in tube bundles with longitudinal flow, Rod bundles: Rohsenow correlation, for nucleate boiling, Roll cells, in free convection, Roller expansion, of tubes into tube sheets, Rose, J W, Rossby number, Rotary dryer, Rotating drums, heat transfer to particle bed in, Rotating surface, in an annular duct Rotation, as device for heat transfer augmentation, Roughness, surface: Rough walled passages, radiative heat transfer down, Rubber (sponge) balls, in fouling mitigation, Ryznar index for water quality,
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Reversible (minimum) work for some processes

DOI 10.1615/hedhme.a.000133

1.9.4 Reversible (minimum) work for some processes

The overall shaft work or exergy required by any process consists of the minimum reversible work — plus the work to offset irreversible losses. The latter is exergy which is completely destroyed in achieving the objectives of the process or piece of equipment — within the constraints of real equipment of finite size.

Certain processes or process steps arise very frequently:

  • Separation of a feed into two or more products of given purities.

  • Liquefaction of a normally gaseous substance.

  • Compression of a gas stream.

  • Carrying out a reaction.

A. Reversible work of separation

A mixture of different chemical species has a greater degree of randomness or disorder — a higher entropy — than the pure components of which it is comprised under the same temperature and pressure. “Un-mixing” this stream into its pure components results in a reduction in entropy. The 2nd Law tells us this cannot occur spontaneously but requires a minimum input of work:

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