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A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
F-correction method: F-factor charts and equations for various heat exchanger configurations, F-factor method: F-type shells: Fabrication: Failure modes of heat exchangers, Falling films, direct contact heat transfer in, Falling film evaporator: Fanno flow, Fans in air-cooled heat exchangers: Fatigue as failure mode of a heat exchanger Fatigue life, of expansion bellows, Fawcett, R Fedor's method, for critical temperature, Fenghour, A Ferritic stainless steels, as material of construction, Fick's law for diffusion, Film boiling: Film model, condenser design by Film temperature, definition of for turbulent flow over flat plate, Films in heat exchangers, Filmwise condensation: Fincotherm, heat transfer medium, Finite-difference equations: Finite difference methods: Finite-element methods: Fins (see also Extended surfaces): Fire-tube boiler, Fired heaters, Fires, room, radiation interaction phenomena in, Firsova, E V, Fixed beds: Fixed tubesheet, shell-and-tube exchangers: Flanges, mechanical design of in heat exchangers, Flash evaporation Flat absorber of thermal radiation, Flat heads: Flat plate: Flat reflector of thermal radiation, Floating head designs for shell-and-tube heat exchangers: Flooded type evaporator, in refrigeration, Flooding phenomena: Flow distribution: Flow-induced vibration, Flow regimes: Flow stream analysis method for segmentally baffled shell and tube heat exchangers, Flue gases, fouling by, Fluid elastic instability as source of flow-induced vibration, Fluid flow, lost work in, Fluid mechanics, Eulerian formulation for, Fluid-to-particle heat transfer in fluidized beds, Fluidized bed dryer: Fluidized bed gravity conveyors, Fluidized beds: Fluids: Fluorine: Fluorobenzene: Fluoroethane (Refrigerant 161): Fluoromethane (Refrigerant 41): Fluted tubes: Flux method, for modeling radiation in furnaces, Flux relationships in heat exchangers, Fogging in condensation Food processing, fouling of heat exchangers in, Forced flow reboilers: Formaldehyde: Formamide: Formic acid: Forster and Zuber correlation for nucleate boiling, Fouling, Foam systems, heat transfer in, Four phase flows, examples, Fourier law for conduction Fourier number (Fo): Frames for plate heat exchangers, France, guide to national practice for mechanical design, Free convection: Free-fall velocity, of particles, Free-stream turbulence, effect on flow over cylinders, Freeze protection of air-cooled heat exchangers, Freezing, of condensate in condensers Fresnel relations in reflection of radiation, Fretting corrosion, Friction factor: Friction multipliers in gas-liquid flow: Friction velocity, definition, Friedel correlation for frictional pressure gradient in straight channels, Froude number: Fuels, properties of, Fuller, R K, Furan: Furfural: Furnaces: Fusion welding, of tubes into tubesheets in shell-and-tube heat exchangers,

Index

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A B C D E F
F-correction method: F-factor charts and equations for various heat exchanger configurations, F-factor method: F-type shells: Fabrication: Failure modes of heat exchangers, Falling films, direct contact heat transfer in, Falling film evaporator: Fanno flow, Fans in air-cooled heat exchangers: Fatigue as failure mode of a heat exchanger Fatigue life, of expansion bellows, Fawcett, R Fedor's method, for critical temperature, Fenghour, A Ferritic stainless steels, as material of construction, Fick's law for diffusion, Film boiling: Film model, condenser design by Film temperature, definition of for turbulent flow over flat plate, Films in heat exchangers, Filmwise condensation: Fincotherm, heat transfer medium, Finite-difference equations: Finite difference methods: Finite-element methods: Fins (see also Extended surfaces): Fire-tube boiler, Fired heaters, Fires, room, radiation interaction phenomena in, Firsova, E V, Fixed beds: Fixed tubesheet, shell-and-tube exchangers: Flanges, mechanical design of in heat exchangers, Flash evaporation Flat absorber of thermal radiation, Flat heads: Flat plate: Flat reflector of thermal radiation, Floating head designs for shell-and-tube heat exchangers: Flooded type evaporator, in refrigeration, Flooding phenomena: Flow distribution: Flow-induced vibration, Flow regimes: Flow stream analysis method for segmentally baffled shell and tube heat exchangers, Flue gases, fouling by, Fluid elastic instability as source of flow-induced vibration, Fluid flow, lost work in, Fluid mechanics, Eulerian formulation for, Fluid-to-particle heat transfer in fluidized beds, Fluidized bed dryer: Fluidized bed gravity conveyors, Fluidized beds: Fluids: Fluorine: Fluorobenzene: Fluoroethane (Refrigerant 161): Fluoromethane (Refrigerant 41): Fluted tubes: Flux method, for modeling radiation in furnaces, Flux relationships in heat exchangers, Fogging in condensation Food processing, fouling of heat exchangers in, Forced flow reboilers: Formaldehyde: Formamide: Formic acid: Forster and Zuber correlation for nucleate boiling, Fouling, Foam systems, heat transfer in, Four phase flows, examples, Fourier law for conduction Fourier number (Fo): Frames for plate heat exchangers, France, guide to national practice for mechanical design, Free convection: Free-fall velocity, of particles, Free-stream turbulence, effect on flow over cylinders, Freeze protection of air-cooled heat exchangers, Freezing, of condensate in condensers Fresnel relations in reflection of radiation, Fretting corrosion, Friction factor: Friction multipliers in gas-liquid flow: Friction velocity, definition, Friedel correlation for frictional pressure gradient in straight channels, Froude number: Fuels, properties of, Fuller, R K, Furan: Furfural: Furnaces: Fusion welding, of tubes into tubesheets in shell-and-tube heat exchangers,
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Vapour Pressure, Enthalpies of Vaporisation and Boiling and Melting Points of Pure Fluids

DOI 10.1615/hedhme.a.000500

5.1 PROPERTIES OF PURE FLUIDS
5.1.3 Vapour pressures, enthalpies of vaporisation and boiling and melting points of pure fluids

A. Introduction

In this section we examine how to estimate vapour pressures, enthalpies of vaporisation and boiling and melting temperatures of pure fluids. These properties play an important role in the design and operation of many chemical and physical processes.

B. Vapour pressure

The work of Boublik et al. (1984) constitutes an excellent source of experimental data for more than 1,000 substances. Data are usually correlated as a function of temperature using either the Antoine equation or the more accurate Wagner equation. The Antoine equation is obtained from the Clapeyron equation and should only be used over the range of temperatures over which the coefficients A, B, and C have been determined. It is usually presented as:

\[\label{eq1} \ln(p/p^0)=A-\dfrac{B}{T+C}\,. \tag{1}\]

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