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A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
F-correction method: F-factor charts and equations for various heat exchanger configurations, F-factor method: F-type shells: Fabrication: Failure modes of heat exchangers, Falling films, direct contact heat transfer in, Falling film evaporator: Fanno flow, Fans in air-cooled heat exchangers: Fatigue as failure mode of a heat exchanger Fatigue life, of expansion bellows, Fawcett, R Fedor's method, for critical temperature, Fenghour, A
Critical Constants of Pure Components Density of Pure Fluids Vapour Pressure, Enthalpies of Vaporisation and Boiling and Melting Points of Pure Fluids Viscosity of Pure Fluids Surface Tension of Pure Liquids Phase Behaviour of Mixtures Surface Tension of Liquid Mixtures Critical Properties of Mixtures
Ferritic stainless steels, as material of construction, Fick's law for diffusion, Film boiling: Film model, condenser design by Film temperature, definition of for turbulent flow over flat plate, Films in heat exchangers, Filmwise condensation: Fincotherm, heat transfer medium, Finite-difference equations: Finite difference methods: Finite-element methods: Fins (see also Extended surfaces): Fire-tube boiler, Fired heaters, Fires, room, radiation interaction phenomena in, Firsova, E V, Fixed beds: Fixed tubesheet, shell-and-tube exchangers: Flanges, mechanical design of in heat exchangers, Flash evaporation Flat absorber of thermal radiation, Flat heads: Flat plate: Flat reflector of thermal radiation, Floating head designs for shell-and-tube heat exchangers: Flooded type evaporator, in refrigeration, Flooding phenomena: Flow distribution: Flow-induced vibration, Flow regimes: Flow stream analysis method for segmentally baffled shell and tube heat exchangers, Flue gases, fouling by, Fluid elastic instability as source of flow-induced vibration, Fluid flow, lost work in, Fluid mechanics, Eulerian formulation for, Fluid-to-particle heat transfer in fluidized beds, Fluidized bed dryer: Fluidized bed gravity conveyors, Fluidized beds: Fluids: Fluorine: Fluorobenzene: Fluoroethane (Refrigerant 161): Fluoromethane (Refrigerant 41): Fluted tubes: Flux method, for modeling radiation in furnaces, Flux relationships in heat exchangers, Fogging in condensation Food processing, fouling of heat exchangers in, Forced flow reboilers: Formaldehyde: Formamide: Formic acid: Forster and Zuber correlation for nucleate boiling, Fouling, Foam systems, heat transfer in, Four phase flows, examples, Fourier law for conduction Fourier number (Fo): Frames for plate heat exchangers, France, guide to national practice for mechanical design, Free convection: Free-fall velocity, of particles, Free-stream turbulence, effect on flow over cylinders, Freeze protection of air-cooled heat exchangers, Freezing, of condensate in condensers Fresnel relations in reflection of radiation, Fretting corrosion, Friction factor: Friction multipliers in gas-liquid flow: Friction velocity, definition, Friedel correlation for frictional pressure gradient in straight channels, Froude number: Fuels, properties of, Fuller, R K, Furan: Furfural: Furnaces: Fusion welding, of tubes into tubesheets in shell-and-tube heat exchangers,

Index

HEDH
A B C D E F
F-correction method: F-factor charts and equations for various heat exchanger configurations, F-factor method: F-type shells: Fabrication: Failure modes of heat exchangers, Falling films, direct contact heat transfer in, Falling film evaporator: Fanno flow, Fans in air-cooled heat exchangers: Fatigue as failure mode of a heat exchanger Fatigue life, of expansion bellows, Fawcett, R Fedor's method, for critical temperature, Fenghour, A
Critical Constants of Pure Components Density of Pure Fluids Vapour Pressure, Enthalpies of Vaporisation and Boiling and Melting Points of Pure Fluids Viscosity of Pure Fluids Surface Tension of Pure Liquids Phase Behaviour of Mixtures Surface Tension of Liquid Mixtures Critical Properties of Mixtures
Ferritic stainless steels, as material of construction, Fick's law for diffusion, Film boiling: Film model, condenser design by Film temperature, definition of for turbulent flow over flat plate, Films in heat exchangers, Filmwise condensation: Fincotherm, heat transfer medium, Finite-difference equations: Finite difference methods: Finite-element methods: Fins (see also Extended surfaces): Fire-tube boiler, Fired heaters, Fires, room, radiation interaction phenomena in, Firsova, E V, Fixed beds: Fixed tubesheet, shell-and-tube exchangers: Flanges, mechanical design of in heat exchangers, Flash evaporation Flat absorber of thermal radiation, Flat heads: Flat plate: Flat reflector of thermal radiation, Floating head designs for shell-and-tube heat exchangers: Flooded type evaporator, in refrigeration, Flooding phenomena: Flow distribution: Flow-induced vibration, Flow regimes: Flow stream analysis method for segmentally baffled shell and tube heat exchangers, Flue gases, fouling by, Fluid elastic instability as source of flow-induced vibration, Fluid flow, lost work in, Fluid mechanics, Eulerian formulation for, Fluid-to-particle heat transfer in fluidized beds, Fluidized bed dryer: Fluidized bed gravity conveyors, Fluidized beds: Fluids: Fluorine: Fluorobenzene: Fluoroethane (Refrigerant 161): Fluoromethane (Refrigerant 41): Fluted tubes: Flux method, for modeling radiation in furnaces, Flux relationships in heat exchangers, Fogging in condensation Food processing, fouling of heat exchangers in, Forced flow reboilers: Formaldehyde: Formamide: Formic acid: Forster and Zuber correlation for nucleate boiling, Fouling, Foam systems, heat transfer in, Four phase flows, examples, Fourier law for conduction Fourier number (Fo): Frames for plate heat exchangers, France, guide to national practice for mechanical design, Free convection: Free-fall velocity, of particles, Free-stream turbulence, effect on flow over cylinders, Freeze protection of air-cooled heat exchangers, Freezing, of condensate in condensers Fresnel relations in reflection of radiation, Fretting corrosion, Friction factor: Friction multipliers in gas-liquid flow: Friction velocity, definition, Friedel correlation for frictional pressure gradient in straight channels, Froude number: Fuels, properties of, Fuller, R K, Furan: Furfural: Furnaces: Fusion welding, of tubes into tubesheets in shell-and-tube heat exchangers,
G H I J K L M N O P Q R S T U V W X Y Z
F Fenghour, A
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Phase Behaviour of Mixtures

DOI 10.1615/hedhme.a.000503

5.2 PROPERTIES OF MIXTURES OF FLUIDS
5.2.1. Density of fluid mixtures

A. Fenghour

A. Introduction

Practical methods for the calculation of the density of gas and liquid mixtures as a function of temperature and pressure are presented in this section. The methods are illustrated with worked examples and the results compared with experimental data. Methods based on the corresponding states principle are quite accurate and can be used up to high pressure, of the order of several hundred bar. The virial approach is accurate at low pressures but its performance worsens with increasing pressure and is not recommended above about 50 bar. For saturated liquid mixtures the correlations proposed by Hankinson and Thomson (1979) and Spencer and Danner (1973) are recommended. For compressed liquid mixtures the method of Thomson et al. (1982) is quite accurate. Only methods which are easy to implement have been selected. More elaborate thermodynamic models such as equations of state, which in principle allow the calculation of all the thermodynamic properties of single substances or mixtures, are beyond the scope of this article because their implementation would require the development of computer programs with lengthy testing periods. Wherever possible guidelines on the accuracy of the recommended methods are provided.

B. Gas mixtures

(a) Corresponding states principle

In the application of the corresponding states principle to mixtures it is necessary first to determine the pseudocritical parameters of the mixture of interest. In Section 508 it is shown how to estimate these scaling parameters through a process of averaging of the constants of the pure constituent components. Once the pseudocritical parameters of a given mixture have been determined, the procedure outlined in Section 499B can be used. This procedure treats the mixture as a fictitious substance, or pseudo-component, when its compression factor Zm(Tr,pr) at reduced conditions of temperature and pressure is given by the following three-parameter correlation (Pitzer et al., 1955):

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