527--Constants for Binary Mixtures

doi:10.1615/hedhme.a.000527

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Baffle leakage in shell-and-tube heat exchangers: Baffles in shell-and-tube heat exchangers: Baker flow regime map for horizontal gas-liquid flow, Balance equation (applied to complete equipment), Band dryer: Bandel and Schlunder correlations, for boiling in horizontal tubes, Basket-type evaporator, Barbosa, J R Jr, Bateman, G, Bayonet tube heat exchangers, constructional features of, Bayonet tube evaporators, Beaton, C F, Beer-Lambert law, Bejan, A, Bell-Delaware method for shell-side heat transfer and pressure drop in shell-and-tube heat exchangers, Bell and Ghaly method for calculation of multicomponent condensation, Benard cells in free convection in horizontal fluid layers, Bends: Benzaldehyde: Benzene: Benzoic acid: Benzonitrile: Benzophenone: Benzyl alcohol: Benzyl chloride: Berenson equation for pool film boiling from a horizontal surface, Bergles, Arthur E, Bernoulli equation, application to flow across cylinders, Bimetallic tubes: Binary mixtures:

bubble growth in, bubble nucleation in, condensation of, condensation of, forming immiscible condensates,

Condensation of Vapour Mixtures Forming Immicible Liquids It's an article azeotropic condensation, constants for, for use in calculation of multicomponent systems,

Constants for Binary Mixtures It's an article

forced convection boiling of, phase equilibria in, pool boiling of,

Bingham fluid (non-Newtonian), Biofouling, Biot number: Biphenyl: Bismarck A, Black liquor, in pulp and paper industry, fouling of heat exchangers by, Black surface: Blackbody radiation, Blades, in scraped surface heat exchangers, Blake-Carmen-Kozeny equation, Blasius equation for friction factor, Blenkin, R, Blunt bodies, drag coefficients for, Boilers: Boiling: Boiling curve: Boiling length: Boiling number, definition, Boiling point, normal, Boiling range (in multicomponent mixtures): Boiling surface in boiling in vertical tubes, Boiling Water Reactor (BWR), fouling problems in, Bolted channel head in shell-and-tube exchanger, Bolted cone head in shell-and-tube heat exchanger, Bolted joints, thermal contact resistance in, Bolting, Bolting of flanges in shell-and-tube heat exchangers, Boltzmann's constant, Bonnet head, in shell-and-tube heat exchanger, Borishanski, V M, Borishanski correlation for nucleate pool boiling, Bott, T R, Boundary layer: Boussinesq approximations: Boussinesq number, definition, Bowring correlations for critical heat flux, Bracket supports for heat exchangers: Brauner, N, Brazed plate exchanger, Brazing in plate fin heat exchanger construction, Bricks, drying of, Brine recirculation, in multistage flash-evaporation, Brinkman number, Brittle fracture, Bromine: Bromley equation for film boiling from horizontal cylinders, Bromobenzene: Bromoethane: Bromomethane: Bromotrifluoromethane (Refrigerant 13B1): Brush and cage system, for fouling mitigation, BS 5500 code for mechanical design of shell-and-tube heat exchangers (see also PD 5500), Bubble crowding as mechanism of critical heat flux, Bubble flow: Bubbles: Bulk viscosity, Bundle-induced convection in kettle reboilers, Bundle layout, in condensers Buoyancy effects: Buoyancy-induced flow in channels, free convective heat transfer with, Busemann-Crocco integral, application in boundary layer equations, 1,2-Butadiene: 1,3-Butadiene: Butane: 1-Butanol: 2-Butanol: Butene-1: cis-2-Butene: trans-2-Butene: Butterworth, D, Butyl acetate: t-Butyl alcohol: Butylamine: Butylbenzene: n-Butylbenzene: n-Butylcyclohexane: Butylcyclopentane: Butylene oxide: Butyr-aldehyde: Butyric acid: Butyronitrile: Bypass (shell-and-tube bundle):

Index

HEDH

A B

bubble growth in, bubble nucleation in, condensation of, condensation of, forming immiscible condensates,

Condensation of Vapour Mixtures Forming Immicible Liquids It's an article azeotropic condensation, constants for, for use in calculation of multicomponent systems,

Constants for Binary Mixtures It's an article

forced convection boiling of, phase equilibria in, pool boiling of,

C D E F G H I J K L M N O P Q R S T U V W X Y Z

B Binary mixtures: condensation of, forming immiscible condensates, constants for, for use in calculation of multicomponent systems,

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Constants for Binary Mixtures

DOI 10.1615/hedhme.a.000527

5.5 PHYSICAL PROPERTY DATA TABLES
5.5.4 Constants for binary mixtures

R.N. Maddox

This section supplies the constants necessary for prediction of nonideal behavior using the Analytical Solution Of Groups (Table 1a—Table 1k). UNIFAC (Table 2a and Table 2b) and Parameters From Group Contributions (Table 3). Methods discussed in Section 504B.

Table 1a Parameters for use in the analytical solution of groups

Group pair	Compounds	Assignments
Alcohol-hydrocarbon-water systems at 60 °C (1)
Group pair	Compounds	CH₂	OH	FH
CH₂	Hexane	6.0		6.0
OH	Water		1.4	1.0
	Water		1.4	1.0
	Pentane	5.0		5.0
	Methanol	1.0	1.0	2.0
	Water		1.4	1.0
	Heptane	7.0		7.0
	Butanol	4.0	1.0	5.0
Parameters
CH₂		1.0	0.305
OH		0.0147	1.0

Table 1b Parameters for use in the analytical solution of groups

Group pair	Compounds	Assignments
Methanol-glycerol systems (1)
Group pair	Compounds	CH₂	OH	GOH	FH
CH₂–	Glycerol			6.0	6.0
Glycerol				6.0	6.0
OH–	Methanol	1.0	1.0		2.0
Glycerol
Calc.	Water		1.4		1.0
	Glycerol			6.0	6.0
Parameters
CH₂		1.0	0.305	0.353
OH		0.0147	1.0	1.095
Glycerol		0.0153	0.991	1.0

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Constants for Binary Mixtures

5.5 PHYSICAL PROPERTY DATA TABLES5.5.4 Constants for binary mixtures

R.N. Maddox

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5.5 PHYSICAL PROPERTY DATA TABLES
5.5.4 Constants for binary mixtures