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Vacuum equipment, operational problems of, Vacuum operation, of reboilers, Valle, A, Valves: Vaned bends, single-phase flow and pressure drop in, Vapor blanketing, as mechanism of critical heat flux, Vapor injection, effect of on boiling heat transfer in tube bundles, Vapor-liquid disengagement, in kettle reboilers, Vapor-liquid separation, for evaporators, Vapor mixtures, condensation of, Vapor pressure, Vapor recompression, in evaporation, Vaporization, choice of evaporator type for, Vaporizer, double bundle, constructional features, Vapors, saturation properties of, Vapors, properties of superheated, Vasiliev, L, Vassilicos, J C, Velocity defect law: Velocity distribution: Velocity fluctuations, in turbulent pipe flow, Velocity ratio (slip ratio): Venting of condensers Vertical condensers: Vertical cylindrical fired heater, Vertical pipes: Vertical surfaces: Vertical thermosiphon reboilers: Vessels of non-circular cross section, design to ASME VIII code, Vessels of rectangular cross section, EN13445 guidance for, Vetere method, for enthalpy of vaporisation, Vibrated beds, heat transfer to, Vibration: Vinyl acetate: Vinyl benzene: Vinyl chloride: Virial equation: Virk equation for maximum drag reduction, Visco-elastic fluids, flow of, Viscometric functions (non-Newtonian flow), methods of determining, Viscosity: Viscosity number (Vi), Viscous dissipation, influence on heat transfer in non-Newtonian flows, Viscous heat generation, in scraped sauce heat exchangers, Viscous sublayer, in duct flow, Void fraction, Voidage, in fixed beds, definition, Volumetric heat transfer coefficient, Volumetric mass transfer coefficient, von Karman friction factor equation for fully rough surface, von Karman velocity defect law, Vortex flow, in helical coils of rectangular cross section, Vortex flow model, for twisted tube heat exchangers, Vortex shedding:
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Heat Transfer for non-Newtonian Fluids

DOI 10.1615/hedhme.a.000179

2.5.12 Heat transfer for non-Newtonian fluids

A. Introduction

(by R. C. Armstrong and H. H. Winter)

Section 179 describes ways in which heat transfer in non-Newtonian fluids is different from that in Newtonian fluids. As polymers constitute the largest class of non-Newtonian fluids, we shall focus our attention on them. Moreover, we shall focus on differences in heat transfer characteristics between Newtonian and polymeric fluids that can be attributed to differences in viscous behavior between these two classes of fluids. These distinctions involve both the shear rate dependence that is commonly observed in non-Newtonian fluids and also the different magnitude of the viscosity in polymers as opposed to low-molecular-weight fluids. In addition to these viscous effects, it is clearly possible that many interesting changes in heat transfer problems could result from the "elastic" character of polymeric fluids. For example, in duct flows involving noncircular cross sections, certain non-Newtonian fluids show qualitatively different secondary velocity patterns than Newtonian fluids. These clearly have some effect on heat transfer. Very little can yet be said quantitatively about these "elastic" effects, however.*

In addition to these differences in heat transfer between Newtonian and non-Newtonian fluids, there are differences in the kinds of information that we are generally interested in for nonisothermal flows of these two classes of fluids. Let us break the possible calculations into two categories: global and local. For Newtonian fluids it is the global result, the evaluation of a heat transfer coefficient to relate bulk temperature differences to heat fluxes, that is of most interest. This heat transfer coefficient, which is used for sizing heat exchanger equipment and estimating bulk temperature changes, is not as useful for non-Newtonian fluids for two reasons: first, in problems with significant viscous heating, which are common for molten polymers, the heat transfer coefficient cannot be defined meaningfully; and second, because of the peculiar physical properties of polymers, heat transfer between a flowing polymer and its surroundings is generally ignored. There are, of course, exceptions to this last statement, such as cooling extruders for low-temperature extrusion of foamed polymers and cooling of polymerization reactors.

For polymeric fluids, evaluation of the local temperature field is usually of primary interest. Because of the sensitivity of the physical properties to temperature, the temperature field can have a pronounced effect on the flow field and therefore on the process itself. In addition, many polymers are temperature sensitive and will degrade at high temperatures, say, at Tdegrad. It is important to be sure that the local temperature never exceeds Tdegrad. Finally, relaxation phenomena in polymers are strongly temperature sensitive, and the amount and location of residual stress or strain in a polymeric product will depend on the local temperature history of the polymer.

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