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A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
Damage, sources of heat exchangers Damkohler number: Damping: Davis and Anderson criterion, for onset of nucleate boiling, Decal, heat transfer medium, Decane: 1-Decanol: 1-Decene: Degradation temperature, of polymers, Demisters, wire mesh, for multistage flash evaporators, Dengler and Addoms correlation, for forced convective heat transfer in two-phase flow, Density: Deposition of droplets in annular flow Deposition in fouling, Desalination plants: Desuperheaters for use in association with evaporators, Developing flow in ducts: Dew-poin corrosion, Diathermanous fluid, 1,1-Dibromoethane: Dibromomethane: 1,2-Dibromotetrafluoroethane (Refrigerant 114B2): Dibutylamine: Dibutyl ether: Dichloroacetic acid: o-Dichlorobenzene: Dichlorodifluoromethane (see Refrigerant 12) 1,1-Dichloroethane (Refrigerant 150a): 1,2-Dichloroethane (Refrigerant 150): 1,1-Dichloroethylene: cis-1,2-Dichloroethylene: trans-1,2-Dichloroethylene: Dichlorofluoromethane (see Refrigerant 21) Dichloromethane (Refrigerant 30): 1,2-Dichlorotetrafluoroethane (Refrigerant 114) 1,2,3-Dichlorotrifluoroethane (Refrigerant 123) Dielectric constant, of water, Diethylamine: n,n-Diethylaniline: Diethylene glycol: Diethyl ether: Diethyl ketone: Diethylsulfide: Differential condensation: Differential formulations for nonisothermal gas radiation, Differential resistance term in heat exchanger design, Differential vector operators in heat conduction, Diffraction models for radiative heat transfer from surfaces, Diffuse surfaces, radiative heat transfer between, Diffuse wall passages, radiative heat transfer in, Diffusers, single-phase flow and pressure drop in, Diffusion, in multi-component condensation, n,n-Diffusion coefficients: 1,1-Difluoroethane (Refrigerant 152a): Difluoromethane (Refrigerant 32): Diiodomethane: Diisobutylamine: Diisopropylamine: Diisopropylether: Dimensional analysis: Dimensionless groups: Dimethylacetylene: Dimethylamine: Dimethylaniline: 2,2-Dimethylbutane: 2,3-Dimethylbutane: 1,1-Dimethylcyclopentane: Dimethylether: Dimethylketone: 2,2-Dimethylpropane (neopentane): Dimethylsulfide: Dimpled surfaces, heat exchangers with, 1,4-Dioxane: Diphenyl: Diphenylamine: Diphenylether: Diphenylmethane: Dipropyl ether: Diisopropyl ether: Dipropyl ketone: Direct contact heat exchangers Direct contact heat transfer, Direct numerical simulation, of turbulence, Dirichlet boundary condition, finite difference method, Dished heads: Discretization in numerical analysis: Disk-and-doughnut baffled heat exchangers, Disks, free convective heat transfer from inclined, Dispersants, for fouling control, Dispersed flow (liquid-liquid), Dissipation of turbulent energy, Distillation: Distribution: Dittus-Boelter equation, for single-phase forced convective heat transfer, Dividing flow, loss coefficients in, Dodecane: 1-Dodecene: Donohue method, for shell-side heat transfer in shell-and-tube heat exchangers, Double-pipe heat exchangers: Double segmental baffled heat exchangers, Downward facing surfaces, free convective heat transfer from, Downward flow in vertical tubes, flow patterns in gas/liquid, Dowtherm A: Dowtherm J: Dowtherms, as heat transfer media, Drag coefficient: Drag force: Drag reduction, Drainage, of condensate, Dreitser, G, Drift flux model for two-phase flows, Drogemuller, P, Droplets: Dropwise condensation Dry wall desuperheating (in condensation), Dryers: Drying loft, Drying rates, prediction of, Dryout: Ducts, single-phase fluid flow and pressure drop in, Duplex stainless steels, Durand correlation for heterogeneous conveyance in solid/liquid flow, Dynamically stable foam, Dyphyl, heat transfer media, Dzyubenko, B,

Index

HEDH
A B C D
Damage, sources of heat exchangers Damkohler number: Damping: Davis and Anderson criterion, for onset of nucleate boiling, Decal, heat transfer medium, Decane: 1-Decanol: 1-Decene: Degradation temperature, of polymers, Demisters, wire mesh, for multistage flash evaporators, Dengler and Addoms correlation, for forced convective heat transfer in two-phase flow, Density: Deposition of droplets in annular flow Deposition in fouling, Desalination plants: Desuperheaters for use in association with evaporators, Developing flow in ducts: Dew-poin corrosion, Diathermanous fluid, 1,1-Dibromoethane: Dibromomethane: 1,2-Dibromotetrafluoroethane (Refrigerant 114B2): Dibutylamine: Dibutyl ether: Dichloroacetic acid: o-Dichlorobenzene: Dichlorodifluoromethane (see Refrigerant 12) 1,1-Dichloroethane (Refrigerant 150a): 1,2-Dichloroethane (Refrigerant 150): 1,1-Dichloroethylene: cis-1,2-Dichloroethylene: trans-1,2-Dichloroethylene: Dichlorofluoromethane (see Refrigerant 21) Dichloromethane (Refrigerant 30): 1,2-Dichlorotetrafluoroethane (Refrigerant 114) 1,2,3-Dichlorotrifluoroethane (Refrigerant 123) Dielectric constant, of water, Diethylamine: n,n-Diethylaniline: Diethylene glycol: Diethyl ether: Diethyl ketone: Diethylsulfide: Differential condensation: Differential formulations for nonisothermal gas radiation, Differential resistance term in heat exchanger design, Differential vector operators in heat conduction, Diffraction models for radiative heat transfer from surfaces, Diffuse surfaces, radiative heat transfer between, Diffuse wall passages, radiative heat transfer in, Diffusers, single-phase flow and pressure drop in, Diffusion, in multi-component condensation, n,n-Diffusion coefficients: 1,1-Difluoroethane (Refrigerant 152a): Difluoromethane (Refrigerant 32): Diiodomethane: Diisobutylamine: Diisopropylamine: Diisopropylether: Dimensional analysis: Dimensionless groups: Dimethylacetylene: Dimethylamine: Dimethylaniline: 2,2-Dimethylbutane: 2,3-Dimethylbutane: 1,1-Dimethylcyclopentane: Dimethylether: Dimethylketone: 2,2-Dimethylpropane (neopentane): Dimethylsulfide: Dimpled surfaces, heat exchangers with, 1,4-Dioxane: Diphenyl: Diphenylamine: Diphenylether: Diphenylmethane: Dipropyl ether: Diisopropyl ether: Dipropyl ketone: Direct contact heat exchangers Direct contact heat transfer, Direct numerical simulation, of turbulence, Dirichlet boundary condition, finite difference method, Dished heads: Discretization in numerical analysis: Disk-and-doughnut baffled heat exchangers, Disks, free convective heat transfer from inclined, Dispersants, for fouling control, Dispersed flow (liquid-liquid), Dissipation of turbulent energy, Distillation: Distribution: Dittus-Boelter equation, for single-phase forced convective heat transfer, Dividing flow, loss coefficients in, Dodecane: 1-Dodecene: Donohue method, for shell-side heat transfer in shell-and-tube heat exchangers, Double-pipe heat exchangers: Double segmental baffled heat exchangers, Downward facing surfaces, free convective heat transfer from, Downward flow in vertical tubes, flow patterns in gas/liquid, Dowtherm A: Dowtherm J: Dowtherms, as heat transfer media, Drag coefficient: Drag force: Drag reduction, Drainage, of condensate, Dreitser, G, Drift flux model for two-phase flows, Drogemuller, P, Droplets: Dropwise condensation Dry wall desuperheating (in condensation), Dryers: Drying loft, Drying rates, prediction of, Dryout: Ducts, single-phase fluid flow and pressure drop in, Duplex stainless steels, Durand correlation for heterogeneous conveyance in solid/liquid flow, Dynamically stable foam, Dyphyl, heat transfer media, Dzyubenko, B,
E F G H I J K L M N O P Q R S T U V W X Y Z

Condensation of Vapour Mixtures Forming Immicible Liquids

DOI 10.1615/hedhme.a.000187

2.6 CONDENSATION
2.6.4 Condensation of vapour mixtures forming immiscible liquids

A. Introduction

The author would like to acknowledge the use he has made of the previous article in HEDH, written by R. Sardesai in 1983. However a significant change in approach has been adopted and the present article has been written as a consistent extension to Section 186. Section 186, Webb and McNaught (1980) and Webb (1990) should be read as pre-cursors to the present article.

The formation of a second immiscible condensate phase during condensation can affect the behaviour in a number of ways and reliable design should account for the possibility. Firstly various modes of condensation may occur. Thus it is possible for a single phase condensate to be formed. Vapours, which will form the other phase, act as non-condensing species imposing a greater gas-side resistance. Secondly when both liquid condensates are present the nature of the flow pattern will influence the condensate film heat transfer coefficient.

The various modes of heat transfer which are possible may be identified by consideration of the phase diagram, Figure 1, which applies for the case of mixtures which may be considered fully immiscible as liquids. The state of the mixture may lie in any of the four regions of the diagram, vapour, two-phase with liquid 1 present, two-phase with liquid 2 present or all liquid. Vapour-liquid equilibrium states with liquid 1 and 2 occur along FE and EG respectively, with the azeotrope at E, where vapour and both liquid phases co-exist at equilibrium.

Figure 1 Phase diagram for vapours which form immiscible condensates

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