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A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
F-correction method: F-factor charts and equations for various heat exchanger configurations, F-factor method: F-type shells: Fabrication: Failure modes of heat exchangers, Falling films, direct contact heat transfer in, Falling film evaporator: Fanno flow, Fans in air-cooled heat exchangers: Fatigue as failure mode of a heat exchanger Fatigue life, of expansion bellows, Fawcett, R Fedor's method, for critical temperature, Fenghour, A Ferritic stainless steels, as material of construction, Fick's law for diffusion, Film boiling: Film model, condenser design by
Condensation of Vapour Mixtures Condensation of Vapour Mixtures Forming Immicible Liquids
Film temperature, definition of for turbulent flow over flat plate, Films in heat exchangers, Filmwise condensation: Fincotherm, heat transfer medium, Finite-difference equations: Finite difference methods: Finite-element methods: Fins (see also Extended surfaces): Fire-tube boiler, Fired heaters, Fires, room, radiation interaction phenomena in, Firsova, E V, Fixed beds: Fixed tubesheet, shell-and-tube exchangers: Flanges, mechanical design of in heat exchangers, Flash evaporation Flat absorber of thermal radiation, Flat heads: Flat plate: Flat reflector of thermal radiation, Floating head designs for shell-and-tube heat exchangers: Flooded type evaporator, in refrigeration, Flooding phenomena: Flow distribution: Flow-induced vibration, Flow regimes: Flow stream analysis method for segmentally baffled shell and tube heat exchangers, Flue gases, fouling by, Fluid elastic instability as source of flow-induced vibration, Fluid flow, lost work in, Fluid mechanics, Eulerian formulation for, Fluid-to-particle heat transfer in fluidized beds, Fluidized bed dryer: Fluidized bed gravity conveyors, Fluidized beds: Fluids: Fluorine: Fluorobenzene: Fluoroethane (Refrigerant 161): Fluoromethane (Refrigerant 41): Fluted tubes: Flux method, for modeling radiation in furnaces, Flux relationships in heat exchangers, Fogging in condensation Food processing, fouling of heat exchangers in, Forced flow reboilers: Formaldehyde: Formamide: Formic acid: Forster and Zuber correlation for nucleate boiling, Fouling, Foam systems, heat transfer in, Four phase flows, examples, Fourier law for conduction Fourier number (Fo): Frames for plate heat exchangers, France, guide to national practice for mechanical design, Free convection: Free-fall velocity, of particles, Free-stream turbulence, effect on flow over cylinders, Freeze protection of air-cooled heat exchangers, Freezing, of condensate in condensers Fresnel relations in reflection of radiation, Fretting corrosion, Friction factor: Friction multipliers in gas-liquid flow: Friction velocity, definition, Friedel correlation for frictional pressure gradient in straight channels, Froude number: Fuels, properties of, Fuller, R K, Furan: Furfural: Furnaces: Fusion welding, of tubes into tubesheets in shell-and-tube heat exchangers,

Index

HEDH
A B C D E F
F-correction method: F-factor charts and equations for various heat exchanger configurations, F-factor method: F-type shells: Fabrication: Failure modes of heat exchangers, Falling films, direct contact heat transfer in, Falling film evaporator: Fanno flow, Fans in air-cooled heat exchangers: Fatigue as failure mode of a heat exchanger Fatigue life, of expansion bellows, Fawcett, R Fedor's method, for critical temperature, Fenghour, A Ferritic stainless steels, as material of construction, Fick's law for diffusion, Film boiling: Film model, condenser design by
Condensation of Vapour Mixtures Condensation of Vapour Mixtures Forming Immicible Liquids
Film temperature, definition of for turbulent flow over flat plate, Films in heat exchangers, Filmwise condensation: Fincotherm, heat transfer medium, Finite-difference equations: Finite difference methods: Finite-element methods: Fins (see also Extended surfaces): Fire-tube boiler, Fired heaters, Fires, room, radiation interaction phenomena in, Firsova, E V, Fixed beds: Fixed tubesheet, shell-and-tube exchangers: Flanges, mechanical design of in heat exchangers, Flash evaporation Flat absorber of thermal radiation, Flat heads: Flat plate: Flat reflector of thermal radiation, Floating head designs for shell-and-tube heat exchangers: Flooded type evaporator, in refrigeration, Flooding phenomena: Flow distribution: Flow-induced vibration, Flow regimes: Flow stream analysis method for segmentally baffled shell and tube heat exchangers, Flue gases, fouling by, Fluid elastic instability as source of flow-induced vibration, Fluid flow, lost work in, Fluid mechanics, Eulerian formulation for, Fluid-to-particle heat transfer in fluidized beds, Fluidized bed dryer: Fluidized bed gravity conveyors, Fluidized beds: Fluids: Fluorine: Fluorobenzene: Fluoroethane (Refrigerant 161): Fluoromethane (Refrigerant 41): Fluted tubes: Flux method, for modeling radiation in furnaces, Flux relationships in heat exchangers, Fogging in condensation Food processing, fouling of heat exchangers in, Forced flow reboilers: Formaldehyde: Formamide: Formic acid: Forster and Zuber correlation for nucleate boiling, Fouling, Foam systems, heat transfer in, Four phase flows, examples, Fourier law for conduction Fourier number (Fo): Frames for plate heat exchangers, France, guide to national practice for mechanical design, Free convection: Free-fall velocity, of particles, Free-stream turbulence, effect on flow over cylinders, Freeze protection of air-cooled heat exchangers, Freezing, of condensate in condensers Fresnel relations in reflection of radiation, Fretting corrosion, Friction factor: Friction multipliers in gas-liquid flow: Friction velocity, definition, Friedel correlation for frictional pressure gradient in straight channels, Froude number: Fuels, properties of, Fuller, R K, Furan: Furfural: Furnaces: Fusion welding, of tubes into tubesheets in shell-and-tube heat exchangers,
G H I J K L M N O P Q R S T U V W X Y Z
F Film model, condenser design by
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Condensation of Vapour Mixtures Forming Immicible Liquids

DOI 10.1615/hedhme.a.000187

2.6 CONDENSATION
2.6.4 Condensation of vapour mixtures forming immiscible liquids

David R. Webb

A. Introduction

The author would like to acknowledge the use he has made of the previous article in HEDH, written by R. Sardesai in 1983. However a significant change in approach has been adopted and the present article has been written as a consistent extension to Section 186. Section 186, Webb and McNaught (1980) and Webb (1990) should be read as pre-cursors to the present article.

The formation of a second immiscible condensate phase during condensation can affect the behaviour in a number of ways and reliable design should account for the possibility. Firstly various modes of condensation may occur. Thus it is possible for a single phase condensate to be formed. Vapours, which will form the other phase, act as non-condensing species imposing a greater gas-side resistance. Secondly when both liquid condensates are present the nature of the flow pattern will influence the condensate film heat transfer coefficient.

The various modes of heat transfer which are possible may be identified by consideration of the phase diagram, Figure 1, which applies for the case of mixtures which may be considered fully immiscible as liquids. The state of the mixture may lie in any of the four regions of the diagram, vapour, two-phase with liquid 1 present, two-phase with liquid 2 present or all liquid. Vapour-liquid equilibrium states with liquid 1 and 2 occur along FE and EG respectively, with the azeotrope at E, where vapour and both liquid phases co-exist at equilibrium.

Figure 1 Phase diagram for vapours which form immiscible condensates

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