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A B C D E F G H I J K L M N O P Q R S
Saddle supports, for heat exchangers, Safety factors, Safety, of heat exchangers: Salicyl aldehyde: Salts, heat transfer, as heat transfer media, Sand roughness, equivalent, Santotherm, heat transfer media, Sastri and Rao correlation for surface tension, Saturated boiling: Saturated density: Saturated fluids, tables of physical properties, Saturation pressure, Saturation temperature, Saunders, E A D Sauer, H J Jr, Scale formation in heat exchangers, Scaling approximations, in nonisothermal gas radiation, Scattering bed models, for radiative heat transfer from surfaces, Scattering, interaction phenomena with, Scattering coefficient, Schack wide-band model, for gas radiation properties, Schick and Prausnitz method, for critical volume of mixtures, Schlunder, E U Schmidt, F W Schmidt correlation, for heat transfer in in-line banks of high fin tubes, Schmidt number, Schneider, G E, Schrock and Grossman correlations, for forced convective heat transfer in two-phase flow, Schunk, M Schwier, K, Scraped surfaces: Scaling devices, in shell-and-tube heat exchangers, Seawater physical properties, Seider-Tate equation, for heat transfer in heat exchangers, Selection of heat transfer equipment: Semiconductors, thermal conductivity, Separated flow model: Separation, exergy analysis for, Separators, for use in association with evaporators, Series solutions, for one-dimensional transient conduction, Serrated fins, in plate fin heat exchangers, Shah correlation for boiling, Shah correlation, for boiling in horizontal tubes, Shape factor, in radiative heat transfer between diffuse surfaces, Shear flow, of non-Newtonian fluids, Shear free flow, of non-Newtonian fluids, Shear rate, in fluid, Shear stress: Sheffield, J W, Shelf dryer, Shell-and-tube heat exchanger: Shell-to-baffle clearance, in shell-and-tube heat exchangers, Shells, for shell-and-tube heat exchangers: Sherwood number Shipes, K V, Short-tube vertical evaporator, Sigma phase embrittlement, of stainless steels, Silicate scales, in heat exchangers, Silicone oils, as heat transfer media, physical properties of, Silver method, for calculation of multicomponent condensation, Similarity theory, Simonis, V, Single-phase fluid flow: Single stage flash evaporation (SSF): Singularities, two-phase gas-liquid pressure drop across, Sink, in radiation: Skid-mounted units, specification of, Skin friction coefficient, Skrinska, A, Slab: Sleeves, internal, for expansion bellows, Slot: Slug flow: Slugging, in fluidized beds, Smith, A A, Smith, R, Smith, R A Smith, O, Snell's law, in radiation, Software, for code design, Solar absorber, Solar reflector, Soldered fins, in double pipe exchangers, Solid fuels, properties of, Solids circulation, in fluidized beds, Solid-gas flow: Solid-liquid flow: Solidification: Solids: Solids circulation, in fluidized beds, Soot blowing, Sound velocity: Source, in radiation: Spacers, in shell-and-tube heat exchangers, Spalding, D B, Sparging: Specific enthalpy, Specific entropy: Specific heat capacity, Specific internal energy, Specific volume: Specification of heat exchangers, Spectral absorptivity: Spectral emissivity, in gases, Specular surface, Specular-walled passages, radiative heat transfer in, Spheres: Spherical coordinates, for finite difference equations for conduction, Spherical shells: Spheroids (oblate and prolate), free convective heat transfer from, Spine fins: Spiral heat exchanger: Spirally fluted tubes: Sponge rubber balls, in fouling mitigation, Spray dryers, Sprays, in heat exchangers, Square ducts: Stable equilibrium, of vapor and liquid, Staggered tube banks: Stainless steels, Stanton number Startup: State diagram, for fluidized beds, Static mixers, in heat exchangers, Statically stable foams, Steam, dropwise condensation of, Steam tables, Steam turbine exhaust condensers, Steels, as material of construction, Stefan-Boltzmann constant, Stefan's law, for blackbody radiation, Stegmaier, W, Steiner and Taborek correlation, for forced convective boiling, Stephan and Korner correlation, for boiling of binary mixtures, Stiffeners, PD5500 code guidelines for, Stiffeners, against external pressure, EN13445 guidance on, Stirred beds, heat transfer to, Stirred reactor model, for furnaces, Stone's strongly implicit method, Straight fins (longitudinal fins): Stratified gas-liquid flow: Stratified liquid-liquid-gas flow: Steam analysis methods, for shell-side heat transfer and pressure drop in shell-and-tube heat exchangers, Stress, compressive, in heat exchanger tubes, Stress corrosion cracking, of stainless steels, Stress equation models, for turbulent boundary layers, Stress-strain curve, for solids, Stress tensor: Stresses: Strip baffles, in tube bundles with longitudinal flow, Strouhal number, Subchannel analysis, for critical heat flux in rod bundles, Subcooled boiling: Subcooling: Sublayer, viscous, Submerged combustion, Successive over-under relaxation method for solution of implicit equations, Suction: Suction line exchangers in refrigeration, Sulfur: Sulfur compounds (organic): Sulfur dioxide: Sulfur hexafluoride: Sulfur trioxide: Supercritical fluids: Superficial velocity, in multiphase flow, Superheated gases: Superheated liquid, in metastable state, Superheated vapor, condensation of, on vertical surface, Supersaturation, as cause of fogging in condensers: Suppression of nucleate boiling, Surface catalysis, in augmentation of heat transfer, Surface condensers, Surface finish: Surface, hydraulically smooth, Surface material, effect on fouling, Surface models, in radiative heat transfer, Surface modification for drag reduction, Surface temperature, effect on fouling, Surface tension: Surfactants, in drag reduction, Suspension, radiation interaction phenomena in, Sutherland formula, for viscosity variation with temperature, Sutterby fluid (non-Newtonian), free convective heat transfer to, Swirling flow, in augmentation of heat transfer, Synthetic heat transfer media, Synthetic mixture heat transfer media,
T U V W X Y Z

Gas Radiation Properties

DOI 10.1615/hedhme.a.000208

2.9 HEAT TRANSFER BY RADIATION
2.9.5 Gas radiation properties

A. The equation of transfer

Up to this point, a diathermanous medium has been assumed. In such a medium the radiant intensity I of a stream of photons is unaffected by passage through the medium. More generally, the photons and matter interact. Three processes may be distinguished: (1) net absorption (total absorption minus induced emission), (2) spontaneous emission, and (3) scattering. The latter can be broken down into scattering out of the beam and scattering into the beam. The result is that in slant path increment ds there is an incremental change in intensity dI as pictured in Figure 1. The equation giving dI/ds is named the equation of transfer.

Figure 1 Change of intensity I along incremental path length ds

The absorption, emission, and scattering properties of matter are sometimes characterized by cross sections. For example, visualize a spherical oil droplet such as is sprayed into a combustion chamber. The droplet of radius R has a total surface area of 4πR2, but its projected area is πR2. The latter is said to be the geometric cross section. If one examines the shadow behind a droplet that is large compared to the wavelength, one finds, due to diffraction, a shadow area of 2πR2 but a bright halo contains half of the radiant power missing due to the shadow, half of I dΩ 2πR2. Whether the droplet is large or small, the radiant power missing from the incident beam divided by that incident on an area of πR2 is termed the extinction efficiency Qe. Thus if one considers the halo radiation as scattered, that is, caused to deviate in direction, the extinction efficiency of a large particle is 2; but, if one considers the halo as undeviated, a more reasonable view for engineering power transfer calculations, then Qe is 1 for a large particle.

The power missing from the shadow may have been absorbed, or it may have been scattered into other directions. The fraction scattered into other directions is called the albedo for single scatter ωs. The fraction 1 – ωs is sometimes called the particle emissivity. Actually it would be better called the particle absorptivity, but Kirchhoff’s law is invoked. The quantity ωsQe is called the scattering efficiency Qs, and (1 – ωs)Qe is called the absorption efficiency Qa.

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