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Cabin heater, Caetano, EF Calcium carbonate, fouling of heat exchangers by, Calcium sulphate, fouling of heat exchangers by, CALFLO, heat transfer media, Calorically perfect gas, CANDU Reactor, fouling problems in, Carbon dioxide: Carbon disulfide: Carbon monoxide: Carbon steel: Carbon-manganese steels Carbon-molybdenum steels, Carbon tetrachloride: Carbonyl sulfide: Carboxylic acids: Carnot cycle in refrigeration, Carnot factor, Carreau fluid (non-Newtonian), Carryover of solids in fluidized beds, Cashman, B L, Cast iron, thermal and mechanical properties, Cavitation as source of damage in heat exchangers, Cell method, for heat exchanger effectiveness, Cement kilns, CEN code for pressure vessels, Centrifugal dryer, Ceramics Certification of heat exchangers, Chan, S H, Channel emissivity, Chapman-Rubescin formula for viscosity variation with temperature, Chemical exergy, Chemical formulas of commonly used fluids Chemical industry, fouling of heat exchangers in, Chemical reactions, exergy analysis of, Chemical reaction fouling, Chen correlation for forced convective boiling, Chen method, for enthalpy of vaporisation, Chenoweth, J M, Chevron troughs as corrugation design in plate heat exchangers, Chillers, construction features of, Chilton-Colburn analogy, Chisholm, D Chisholm correlations: Chlorine: Chloroacetic acid: Chlorobenzene: Chlorobutane: Chlorodifluoromethane (see Refrigerant 22) 1-Chloro-1,1-difluoroethane (Refrigerant 142b): Chloroethane (Refrigerant 160): Chloromethane (Refrigerant 40): Chloropentane: 1,2-Chloropentafluoroethane (Refrigerant 115): Chloroprene (2-Chloro-1,3-butadiene): 1-Chloropropane: 2-Chloropropane: m-Chlorotoluene: o-Chlorotoluene: Chlorotrifluoroethylene: Chlorotrifluoromethane (see Refrigerant 13) Chromium-molybdenum steels, Chudnovsky, Y, Chugging flow (gas-liquid), in shell-and-tube heat exchangers, Chung et al method, for viscosity of low pressure gases, Church and Prausnitz methods: Churchill, S W, Churchill and Chu correlations for free convective heat transfer: Churn flow, regions of occurrence of, Circles, radiative heat transfer shape factors between parallel coaxial, Circular girth flanges, design according to ASME VIII code, Circulating fluidized beds, Circulation, modes of in free convection: in enclosures heated from below, CISE correlations for void fractions, Clausius-Clapeyron relationship: Cleaning: Climbing film evaporator, Closed circuit cooling towers, Coalescence of bubbles in fluidized beds, Coatings for corrosion protection Cocurrent flow: Codes, mechanical design: Cogeneration Colburn and Drew method for binary vapor condensation, Colburn and Hougen method for condensation in presence of noncondensable gases Colburn equation for single-phase heat transfer outside tube banks, Colburn j factor: Colebrook-White equation for friction factor in rough circular pipe, Coles, law of the wake, Collier, J G, Combined free and forced convection heat transfer: Combined heat and mass transfer, Combining flow, loss coefficients in, Combustion model for furnaces, Compact heat exchangers (see Plate fin heat exchangers) Compartment dryers, Composite curves, in the pinch analysis method for heat exchanger network analysis: Compressed liquids, density of: Compressible flow: Compression, exergy analysis of Compressive stress, in heat exchanger tubes, Computer-aided design, of evaporators, Computer program for Monte Carlo calculations of radiative heat transfer, Computer simulation, of fouling, Computer software for mechanical design, Concentration, choice of evaporator type for, Concentric spheres, free convective heat transfer in, Concurrency corrections in plate heat exchangers, Condensation: Concrete, lightweight, submerged combustion system for, Condensation curves: Condenser/preheater tubes, in multistage flash evaporation, Condensers: Conduction, heat: Conductors, thermal conductivity of, Cones, under internal pressure, EN13445 guidelines for, Cones, vertical: Conical shells, mechanical design of: Conjugate radiation interactions Connors equation for fluid elastic instability, Conservation equations: Constantinon and Gani method, for estimating normal boiling point, Contact angle, Contact resistance: Continuity equation: Continuum model, for fluids, Continuum theories, for non-Newtonian fluids, Contraction, sudden, pressure drop in: Control: Control volume method, in finite difference solutions for conduction, Convection, interaction of radiation with, Convection effects, on heat transfer in kettle reboilers, Convective heat transfer, single-phase: Conversion factors: Conveyor, gravity: Cooling curves, in condensation, Cooling towers: Cooling water fouling, Cooper correlation, for nucleate boiling, Cooper, Anthony, Copper, thermal and mechanical properties, Copper alloys, Correlation, general nature of, Corresponding states principle Corrosion: Corrugation design, for plate heat exchangers Costing of heat exchangers: Countercurrent flow: Coupled thermal fields, in transient conduction, Cowie, R C, Crank-Nicolson differencing scheme, in finite difference method, Creeping flow, in combined free and forced convection around immersed bodies, m-Cresol: o-Cresol: p-Cresol: Crevice corrosion, in stainless steels, Critical constants Critical density, of commonly used fluids, Critical flow, in gas-liquid systems, Critical heat flux: Critical pressure: Critical Rayleigh number, in free convection, Critical temperature: Critical velocity, in stratification in bends and horizontal tubes, Critical volume (see also Critical density) Cross counterflow heat exchangers, Crossflow: Crude oil, fouling of heat exchangers: Cryogenic plant, entropy generation in, Crystallization Crystallization fouling, Curved ducts: Cut-and-twist factor, in enhancement of heat transfer in double pipe heat exchangers, C-value method for heat exchanger costing, Cycling, of expansion bellows, Cyclobutane: Cyclohexane: Cyclohexanol: Cyclohexene: Cyclopentane: Cyclopentene: Cyclopropane: Cylinders: Cylindrical contacts, thermal contact resistance in, Cylindrical coordinates, finite difference equations for conduction in, Cylindrical shell, analytical basis of code rules for,

Index

HEDH
A B C
Cabin heater, Caetano, EF Calcium carbonate, fouling of heat exchangers by, Calcium sulphate, fouling of heat exchangers by, CALFLO, heat transfer media, Calorically perfect gas, CANDU Reactor, fouling problems in, Carbon dioxide: Carbon disulfide: Carbon monoxide: Carbon steel: Carbon-manganese steels Carbon-molybdenum steels, Carbon tetrachloride: Carbonyl sulfide: Carboxylic acids: Carnot cycle in refrigeration, Carnot factor, Carreau fluid (non-Newtonian), Carryover of solids in fluidized beds, Cashman, B L, Cast iron, thermal and mechanical properties, Cavitation as source of damage in heat exchangers, Cell method, for heat exchanger effectiveness, Cement kilns, CEN code for pressure vessels, Centrifugal dryer, Ceramics Certification of heat exchangers, Chan, S H, Channel emissivity, Chapman-Rubescin formula for viscosity variation with temperature, Chemical exergy, Chemical formulas of commonly used fluids Chemical industry, fouling of heat exchangers in, Chemical reactions, exergy analysis of, Chemical reaction fouling, Chen correlation for forced convective boiling, Chen method, for enthalpy of vaporisation, Chenoweth, J M, Chevron troughs as corrugation design in plate heat exchangers, Chillers, construction features of, Chilton-Colburn analogy, Chisholm, D Chisholm correlations: Chlorine: Chloroacetic acid: Chlorobenzene: Chlorobutane: Chlorodifluoromethane (see Refrigerant 22) 1-Chloro-1,1-difluoroethane (Refrigerant 142b): Chloroethane (Refrigerant 160): Chloromethane (Refrigerant 40): Chloropentane: 1,2-Chloropentafluoroethane (Refrigerant 115): Chloroprene (2-Chloro-1,3-butadiene): 1-Chloropropane: 2-Chloropropane: m-Chlorotoluene: o-Chlorotoluene: Chlorotrifluoroethylene: Chlorotrifluoromethane (see Refrigerant 13) Chromium-molybdenum steels, Chudnovsky, Y, Chugging flow (gas-liquid), in shell-and-tube heat exchangers, Chung et al method, for viscosity of low pressure gases, Church and Prausnitz methods: Churchill, S W, Churchill and Chu correlations for free convective heat transfer: Churn flow, regions of occurrence of, Circles, radiative heat transfer shape factors between parallel coaxial, Circular girth flanges, design according to ASME VIII code, Circulating fluidized beds, Circulation, modes of in free convection: in enclosures heated from below, CISE correlations for void fractions, Clausius-Clapeyron relationship: Cleaning: Climbing film evaporator, Closed circuit cooling towers, Coalescence of bubbles in fluidized beds, Coatings for corrosion protection Cocurrent flow: Codes, mechanical design: Cogeneration Colburn and Drew method for binary vapor condensation, Colburn and Hougen method for condensation in presence of noncondensable gases Colburn equation for single-phase heat transfer outside tube banks, Colburn j factor: Colebrook-White equation for friction factor in rough circular pipe, Coles, law of the wake, Collier, J G, Combined free and forced convection heat transfer: Combined heat and mass transfer, Combining flow, loss coefficients in, Combustion model for furnaces, Compact heat exchangers (see Plate fin heat exchangers) Compartment dryers, Composite curves, in the pinch analysis method for heat exchanger network analysis: Compressed liquids, density of: Compressible flow: Compression, exergy analysis of Compressive stress, in heat exchanger tubes, Computer-aided design, of evaporators, Computer program for Monte Carlo calculations of radiative heat transfer, Computer simulation, of fouling, Computer software for mechanical design, Concentration, choice of evaporator type for, Concentric spheres, free convective heat transfer in, Concurrency corrections in plate heat exchangers, Condensation: Concrete, lightweight, submerged combustion system for, Condensation curves: Condenser/preheater tubes, in multistage flash evaporation, Condensers: Conduction, heat: Conductors, thermal conductivity of, Cones, under internal pressure, EN13445 guidelines for, Cones, vertical: Conical shells, mechanical design of: Conjugate radiation interactions Connors equation for fluid elastic instability, Conservation equations: Constantinon and Gani method, for estimating normal boiling point, Contact angle, Contact resistance: Continuity equation: Continuum model, for fluids, Continuum theories, for non-Newtonian fluids, Contraction, sudden, pressure drop in: Control: Control volume method, in finite difference solutions for conduction, Convection, interaction of radiation with, Convection effects, on heat transfer in kettle reboilers, Convective heat transfer, single-phase: Conversion factors: Conveyor, gravity: Cooling curves, in condensation, Cooling towers: Cooling water fouling, Cooper correlation, for nucleate boiling, Cooper, Anthony, Copper, thermal and mechanical properties, Copper alloys, Correlation, general nature of, Corresponding states principle Corrosion: Corrugation design, for plate heat exchangers Costing of heat exchangers: Countercurrent flow: Coupled thermal fields, in transient conduction, Cowie, R C, Crank-Nicolson differencing scheme, in finite difference method, Creeping flow, in combined free and forced convection around immersed bodies, m-Cresol: o-Cresol: p-Cresol: Crevice corrosion, in stainless steels, Critical constants Critical density, of commonly used fluids, Critical flow, in gas-liquid systems, Critical heat flux: Critical pressure: Critical Rayleigh number, in free convection, Critical temperature: Critical velocity, in stratification in bends and horizontal tubes, Critical volume (see also Critical density) Cross counterflow heat exchangers, Crossflow: Crude oil, fouling of heat exchangers: Cryogenic plant, entropy generation in, Crystallization Crystallization fouling, Curved ducts: Cut-and-twist factor, in enhancement of heat transfer in double pipe heat exchangers, C-value method for heat exchanger costing, Cycling, of expansion bellows, Cyclobutane: Cyclohexane: Cyclohexanol: Cyclohexene: Cyclopentane: Cyclopentene: Cyclopropane: Cylinders: Cylindrical contacts, thermal contact resistance in, Cylindrical coordinates, finite difference equations for conduction in, Cylindrical shell, analytical basis of code rules for,
D E F G H I J K L M N O P Q R S T U V W X Y Z

Environmental Impact of Heat Exchanger Fouling

DOI 10.1615/hedhme.a.000361

3.17 FOULING IN HEAT EXCHANGERS
3.17.5 Environmental impact of heat exchanger fouling

It is not well appreciated that the problem of heat exchanger fouling has wide environmental repercussions. The effect may sometimes be very apparent but much of the impact is less obvious, and is hidden in general industrial activity.

The essential purpose of a heat exchanger as the name implies, is to transfer heat as effectively as possible. In essence in general terms, heat used in industrial processes is derived from a primary fuel source e.g. fossil fuels, biomass or waste combustion. The heat may be recovered directly for use in the process such as in a pipe still on a petroleum refinery. It is perhaps more common for the combustion heat to be used to raise steam for direct use as a heating medium, or in conjunction with a turbine to produce electricity. Inefficiencies principally due to heat transfer surface fouling, occur in the heat transfer processes, that result in the consumption of additional fuel to make up for the shortfall between what is theoretically possible and what is actually achieved in practice.

In order to reduce energy costs, particularly in large scale processing operations, such as a chemical complex or petroleum refinery, it is essential to recover as much heat as possible. The technology involves the transfer of heat contained in hot product streams, which require cooling, to cold streams that need to be heated to satisfy process requirements. In large-scale operations there is likely to be a complex arrangement of heat exchangers that may be optimized by the application of the concept of process integration or pinch technology Linnoff et al.(1982). The effectiveness of the whole heat recovery process however, is dependent on the sum of efficiencies of each individual heat exchanger in the network.

In broad general terms, it ought to be possible to reuse much of the heat involved in processing, except where the heat is used in endothermic reactions, or where the heat becomes degraded to relatively low temperatures. The opportunity to utilize low grade heat is affected by the overall thermal efficiency. The sum of these individual inefficiencies gives rise again, to a short fall in heat recovery that has to be made up from the energy source, ultimately from the combustion of primary fuel.

The efficiency of an individual heat exchanger for a given set of operating conditions of temperature and flow rate, is largely governed by the extent of the fouling experienced on both sides of the exchanger, as described elsewhere in this chapter. In addition to the resistance to heat transfer, the presence of the fouling deposits restricts flow and, for a given throughput will increase the pressure drop through the exchanger. In order to maintain the flow to satisfy process requirements, this will represent an increase in pumping energy. Many industrial systems will use electrically driven pumps, so that the increased energy requirement will ultimately be manifest in increased combustion of fuel.

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