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Rabas and Taborek correlation, for heat transfer in banks of low fin tubes, Rackett equation (modified) for liquid density Radiation: Radiation shields, in radiation heat transfer, Radiation source analysis, Radiative heat transfer: Radiators, automotive, construction, Radiometers, application in gas radiation property measurement, Radiosity, Stephan's law for, Radiosity-irradiation formulations in radiative heat transfer, Rankine cycle in refrigeration, Rao, B K Raoult's law for partial pressure, Rating of heat exchangers, Rayleigh instability, in free convection, Rayleigh number Reay, D Reboilers: Reciprocal mode integrating sphere, for reflection and transmission measurements in radiation, Rectangles: Rectangular ducts: Rectangular enclosures, free convective heat transfer in: Rectangular fins, for plate fin exchangers Reduced pressure, correlations for pool boiling using, Reference temperature: Refinery processes, fouling in, Reflection, of thermal radiation, from solid surfaces: Reflectivity, of solid surfaces, Reflectometer, heated cavity, Reflux condensers, Refractories, density of, Refractory surfaces, Refrigerants: Refrigerant 11 (Trichlorofluoromethane): Refrigerant 12 (Dichlorodifluoromethane): Refrigerant 13 (Chlorotrifluoromethane): Refrigerant 21 (Dichlorofluoromethane): Refrigerant 22 (Chlorodifluoromethane): Refrigerant 116: Refrigerant plant, entropy generation in, Refrigeration, heat transfer in, Regenerators and thermal energy storage, Regimes of heat transfer, in ducts, single phase flow, Reidel method, for predicting enthalpy of vaporisation, Reinforcing rings, for expansion bellows, Relaminarization, of turbulent flow, Reichenberg method, for effect of pressure on gas viscosity, Relief system design for shell-and-tube heat exchangers with tube side failure, Removal of fouling deposits: Renewable fuels, properties of, Renotherm, heat transfer medium, Repair, of expansion bellows, Residence times, in dryers: Resistance network analysis, Resistance (thermal) due to fouling: Reversible (minimum) work, in Reynolds number, Reynolds stress models, for turbulence, Rheologically complex materials, properties of: Rheological properties of drag reducing agents Rheology, shear flow experiments used in, Rhine, J M, Ribatski, G, Riblets for drag reduction, Richardson number, Richie, J M, Ring cells, in free convection, RODbaffles, in tube bundles with longitudinal flow, Rod bundles: Rohsenow correlation, for nucleate boiling, Roll cells, in free convection, Roller expansion, of tubes into tube sheets, Rose, J W, Rossby number, Rotary dryer, Rotating drums, heat transfer to particle bed in, Rotating surface, in an annular duct Rotation, as device for heat transfer augmentation, Roughness, surface: Rough walled passages, radiative heat transfer down, Rubber (sponge) balls, in fouling mitigation, Ryznar index for water quality,
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Thermodynamic cycles

DOI 10.1615/hedhme.a.000398

3.26.2 Thermodynamic cycles

In addition to identifying the natural direction of energy transfer processes, the Second Law of Thermodynamics states that some forms of energy have higher quality than others. Whereas there are no limits for conversion of high-quality energy (e.g. work) into low-quality energy (e.g. heat), the Second Law imposes theoretical limitations for the conversion of heat into work and for the transfer of heat from a low temperature thermal energy reservoir (source) to a high temperature thermal reservoir (sink).

A heat engine, as depicted in Figure 1(a), is a device that operates in a cycle and converts heat into work. The rate of heat input from the high temperature reservoir is H  and part of this heat is converted into work, net. For a system undergoing a cycle, the change in internal energy is zero and the rate of heat rejection to the low temperature reservoir is H  = Lnet.

Figure 1 A schematic representation of (a) a heat engine and (b) a refrigerator or a heat pump

The ratio of the net work output to the total heat input to the heat engine represents the efficiency with which it converts heat into work. The thermal efficiency is defined as,

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