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A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
Damage, sources of heat exchangers Damkohler number: Damping: Davis and Anderson criterion, for onset of nucleate boiling, Decal, heat transfer medium, Decane: 1-Decanol: 1-Decene: Degradation temperature, of polymers, Demisters, wire mesh, for multistage flash evaporators, Dengler and Addoms correlation, for forced convective heat transfer in two-phase flow, Density:
definition, fluid with constant, fluid with small variations of, of fluid mixtures,
Phase Behaviour of Mixtures gases, liquids,
of heat transfer media, of heavy water, of liquid water, of liquids below their boiling point, of multicomponent liquid mixtures, of pure fluids, of saturated liquids and vapors, of seawater, of solids, of superheated fluids, of superheated gases, relation with viscosity for gases,
Deposition of droplets in annular flow Deposition in fouling, Desalination plants: Desuperheaters for use in association with evaporators, Developing flow in ducts: Dew-poin corrosion, Diathermanous fluid, 1,1-Dibromoethane: Dibromomethane: 1,2-Dibromotetrafluoroethane (Refrigerant 114B2): Dibutylamine: Dibutyl ether: Dichloroacetic acid: o-Dichlorobenzene: Dichlorodifluoromethane (see Refrigerant 12) 1,1-Dichloroethane (Refrigerant 150a): 1,2-Dichloroethane (Refrigerant 150): 1,1-Dichloroethylene: cis-1,2-Dichloroethylene: trans-1,2-Dichloroethylene: Dichlorofluoromethane (see Refrigerant 21) Dichloromethane (Refrigerant 30): 1,2-Dichlorotetrafluoroethane (Refrigerant 114) 1,2,3-Dichlorotrifluoroethane (Refrigerant 123) Dielectric constant, of water, Diethylamine: n,n-Diethylaniline: Diethylene glycol: Diethyl ether: Diethyl ketone: Diethylsulfide: Differential condensation: Differential formulations for nonisothermal gas radiation, Differential resistance term in heat exchanger design, Differential vector operators in heat conduction, Diffraction models for radiative heat transfer from surfaces, Diffuse surfaces, radiative heat transfer between, Diffuse wall passages, radiative heat transfer in, Diffusers, single-phase flow and pressure drop in, Diffusion, in multi-component condensation, n,n-Diffusion coefficients: 1,1-Difluoroethane (Refrigerant 152a): Difluoromethane (Refrigerant 32): Diiodomethane: Diisobutylamine: Diisopropylamine: Diisopropylether: Dimensional analysis: Dimensionless groups: Dimethylacetylene: Dimethylamine: Dimethylaniline: 2,2-Dimethylbutane: 2,3-Dimethylbutane: 1,1-Dimethylcyclopentane: Dimethylether: Dimethylketone: 2,2-Dimethylpropane (neopentane): Dimethylsulfide: Dimpled surfaces, heat exchangers with, 1,4-Dioxane: Diphenyl: Diphenylamine: Diphenylether: Diphenylmethane: Dipropyl ether: Diisopropyl ether: Dipropyl ketone: Direct contact heat exchangers Direct contact heat transfer, Direct numerical simulation, of turbulence, Dirichlet boundary condition, finite difference method, Dished heads: Discretization in numerical analysis: Disk-and-doughnut baffled heat exchangers, Disks, free convective heat transfer from inclined, Dispersants, for fouling control, Dispersed flow (liquid-liquid), Dissipation of turbulent energy, Distillation: Distribution: Dittus-Boelter equation, for single-phase forced convective heat transfer, Dividing flow, loss coefficients in, Dodecane: 1-Dodecene: Donohue method, for shell-side heat transfer in shell-and-tube heat exchangers, Double-pipe heat exchangers: Double segmental baffled heat exchangers, Downward facing surfaces, free convective heat transfer from, Downward flow in vertical tubes, flow patterns in gas/liquid, Dowtherm A: Dowtherm J: Dowtherms, as heat transfer media, Drag coefficient: Drag force: Drag reduction, Drainage, of condensate, Dreitser, G, Drift flux model for two-phase flows, Drogemuller, P, Droplets: Dropwise condensation Dry wall desuperheating (in condensation), Dryers: Drying loft, Drying rates, prediction of, Dryout: Ducts, single-phase fluid flow and pressure drop in, Duplex stainless steels, Durand correlation for heterogeneous conveyance in solid/liquid flow, Dynamically stable foam, Dyphyl, heat transfer media, Dzyubenko, B,

Index

HEDH
A B C D
Damage, sources of heat exchangers Damkohler number: Damping: Davis and Anderson criterion, for onset of nucleate boiling, Decal, heat transfer medium, Decane: 1-Decanol: 1-Decene: Degradation temperature, of polymers, Demisters, wire mesh, for multistage flash evaporators, Dengler and Addoms correlation, for forced convective heat transfer in two-phase flow, Density:
definition, fluid with constant, fluid with small variations of, of fluid mixtures,
Phase Behaviour of Mixtures gases, liquids,
of heat transfer media, of heavy water, of liquid water, of liquids below their boiling point, of multicomponent liquid mixtures, of pure fluids, of saturated liquids and vapors, of seawater, of solids, of superheated fluids, of superheated gases, relation with viscosity for gases,
Deposition of droplets in annular flow Deposition in fouling, Desalination plants: Desuperheaters for use in association with evaporators, Developing flow in ducts: Dew-poin corrosion, Diathermanous fluid, 1,1-Dibromoethane: Dibromomethane: 1,2-Dibromotetrafluoroethane (Refrigerant 114B2): Dibutylamine: Dibutyl ether: Dichloroacetic acid: o-Dichlorobenzene: Dichlorodifluoromethane (see Refrigerant 12) 1,1-Dichloroethane (Refrigerant 150a): 1,2-Dichloroethane (Refrigerant 150): 1,1-Dichloroethylene: cis-1,2-Dichloroethylene: trans-1,2-Dichloroethylene: Dichlorofluoromethane (see Refrigerant 21) Dichloromethane (Refrigerant 30): 1,2-Dichlorotetrafluoroethane (Refrigerant 114) 1,2,3-Dichlorotrifluoroethane (Refrigerant 123) Dielectric constant, of water, Diethylamine: n,n-Diethylaniline: Diethylene glycol: Diethyl ether: Diethyl ketone: Diethylsulfide: Differential condensation: Differential formulations for nonisothermal gas radiation, Differential resistance term in heat exchanger design, Differential vector operators in heat conduction, Diffraction models for radiative heat transfer from surfaces, Diffuse surfaces, radiative heat transfer between, Diffuse wall passages, radiative heat transfer in, Diffusers, single-phase flow and pressure drop in, Diffusion, in multi-component condensation, n,n-Diffusion coefficients: 1,1-Difluoroethane (Refrigerant 152a): Difluoromethane (Refrigerant 32): Diiodomethane: Diisobutylamine: Diisopropylamine: Diisopropylether: Dimensional analysis: Dimensionless groups: Dimethylacetylene: Dimethylamine: Dimethylaniline: 2,2-Dimethylbutane: 2,3-Dimethylbutane: 1,1-Dimethylcyclopentane: Dimethylether: Dimethylketone: 2,2-Dimethylpropane (neopentane): Dimethylsulfide: Dimpled surfaces, heat exchangers with, 1,4-Dioxane: Diphenyl: Diphenylamine: Diphenylether: Diphenylmethane: Dipropyl ether: Diisopropyl ether: Dipropyl ketone: Direct contact heat exchangers Direct contact heat transfer, Direct numerical simulation, of turbulence, Dirichlet boundary condition, finite difference method, Dished heads: Discretization in numerical analysis: Disk-and-doughnut baffled heat exchangers, Disks, free convective heat transfer from inclined, Dispersants, for fouling control, Dispersed flow (liquid-liquid), Dissipation of turbulent energy, Distillation: Distribution: Dittus-Boelter equation, for single-phase forced convective heat transfer, Dividing flow, loss coefficients in, Dodecane: 1-Dodecene: Donohue method, for shell-side heat transfer in shell-and-tube heat exchangers, Double-pipe heat exchangers: Double segmental baffled heat exchangers, Downward facing surfaces, free convective heat transfer from, Downward flow in vertical tubes, flow patterns in gas/liquid, Dowtherm A: Dowtherm J: Dowtherms, as heat transfer media, Drag coefficient: Drag force: Drag reduction, Drainage, of condensate, Dreitser, G, Drift flux model for two-phase flows, Drogemuller, P, Droplets: Dropwise condensation Dry wall desuperheating (in condensation), Dryers: Drying loft, Drying rates, prediction of, Dryout: Ducts, single-phase fluid flow and pressure drop in, Duplex stainless steels, Durand correlation for heterogeneous conveyance in solid/liquid flow, Dynamically stable foam, Dyphyl, heat transfer media, Dzyubenko, B,
E F G H I J K L M N O P Q R S T U V W X Y Z
D Density: of fluid mixtures,
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Phase Behaviour of Mixtures

DOI 10.1615/hedhme.a.000503

5.2 PROPERTIES OF MIXTURES OF FLUIDS
5.2.1. Density of fluid mixtures

A. Fenghour

A. Introduction

Practical methods for the calculation of the density of gas and liquid mixtures as a function of temperature and pressure are presented in this section. The methods are illustrated with worked examples and the results compared with experimental data. Methods based on the corresponding states principle are quite accurate and can be used up to high pressure, of the order of several hundred bar. The virial approach is accurate at low pressures but its performance worsens with increasing pressure and is not recommended above about 50 bar. For saturated liquid mixtures the correlations proposed by Hankinson and Thomson (1979) and Spencer and Danner (1973) are recommended. For compressed liquid mixtures the method of Thomson et al. (1982) is quite accurate. Only methods which are easy to implement have been selected. More elaborate thermodynamic models such as equations of state, which in principle allow the calculation of all the thermodynamic properties of single substances or mixtures, are beyond the scope of this article because their implementation would require the development of computer programs with lengthy testing periods. Wherever possible guidelines on the accuracy of the recommended methods are provided.

B. Gas mixtures

(a) Corresponding states principle

In the application of the corresponding states principle to mixtures it is necessary first to determine the pseudocritical parameters of the mixture of interest. In Section 508 it is shown how to estimate these scaling parameters through a process of averaging of the constants of the pure constituent components. Once the pseudocritical parameters of a given mixture have been determined, the procedure outlined in Section 499B can be used. This procedure treats the mixture as a fictitious substance, or pseudo-component, when its compression factor Zm(Tr,pr) at reduced conditions of temperature and pressure is given by the following three-parameter correlation (Pitzer et al., 1955):

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