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A B C D E F G H I J K L M N O P Q R S
Saddle supports, for heat exchangers, Safety factors, Safety, of heat exchangers: Salicyl aldehyde: Salts, heat transfer, as heat transfer media, Sand roughness, equivalent, Santotherm, heat transfer media, Sastri and Rao correlation for surface tension, Saturated boiling: Saturated density: Saturated fluids, tables of physical properties, Saturation pressure, Saturation temperature, Saunders, E A D Sauer, H J Jr, Scale formation in heat exchangers, Scaling approximations, in nonisothermal gas radiation, Scattering bed models, for radiative heat transfer from surfaces, Scattering, interaction phenomena with, Scattering coefficient, Schack wide-band model, for gas radiation properties, Schick and Prausnitz method, for critical volume of mixtures, Schlunder, E U Schmidt, F W Schmidt correlation, for heat transfer in in-line banks of high fin tubes, Schmidt number, Schneider, G E, Schrock and Grossman correlations, for forced convective heat transfer in two-phase flow, Schunk, M Schwier, K, Scraped surfaces: Scaling devices, in shell-and-tube heat exchangers, Seawater physical properties, Seider-Tate equation, for heat transfer in heat exchangers, Selection of heat transfer equipment: Semiconductors, thermal conductivity, Separated flow model: Separation, exergy analysis for, Separators, for use in association with evaporators, Series solutions, for one-dimensional transient conduction, Serrated fins, in plate fin heat exchangers, Shah correlation for boiling, Shah correlation, for boiling in horizontal tubes, Shape factor, in radiative heat transfer between diffuse surfaces, Shear flow, of non-Newtonian fluids, Shear free flow, of non-Newtonian fluids, Shear rate, in fluid, Shear stress: Sheffield, J W, Shelf dryer, Shell-and-tube heat exchanger: Shell-to-baffle clearance, in shell-and-tube heat exchangers, Shells, for shell-and-tube heat exchangers: Sherwood number Shipes, K V, Short-tube vertical evaporator, Sigma phase embrittlement, of stainless steels, Silicate scales, in heat exchangers, Silicone oils, as heat transfer media, physical properties of, Silver method, for calculation of multicomponent condensation, Similarity theory, Simonis, V, Single-phase fluid flow: Single stage flash evaporation (SSF): Singularities, two-phase gas-liquid pressure drop across, Sink, in radiation: Skid-mounted units, specification of, Skin friction coefficient, Skrinska, A, Slab: Sleeves, internal, for expansion bellows, Slot: Slug flow: Slugging, in fluidized beds, Smith, A A, Smith, R, Smith, R A Smith, O, Snell's law, in radiation, Software, for code design, Solar absorber, Solar reflector, Soldered fins, in double pipe exchangers, Solid fuels, properties of, Solids circulation, in fluidized beds, Solid-gas flow: Solid-liquid flow: Solidification: Solids: Solids circulation, in fluidized beds, Soot blowing, Sound velocity: Source, in radiation: Spacers, in shell-and-tube heat exchangers, Spalding, D B, Sparging: Specific enthalpy, Specific entropy: Specific heat capacity, Specific internal energy, Specific volume: Specification of heat exchangers, Spectral absorptivity: Spectral emissivity, in gases, Specular surface, Specular-walled passages, radiative heat transfer in, Spheres: Spherical coordinates, for finite difference equations for conduction, Spherical shells: Spheroids (oblate and prolate), free convective heat transfer from, Spine fins: Spiral heat exchanger: Spirally fluted tubes: Sponge rubber balls, in fouling mitigation, Spray dryers, Sprays, in heat exchangers, Square ducts: Stable equilibrium, of vapor and liquid, Staggered tube banks: Stainless steels, Stanton number Startup: State diagram, for fluidized beds, Static mixers, in heat exchangers, Statically stable foams, Steam, dropwise condensation of, Steam tables, Steam turbine exhaust condensers, Steels, as material of construction, Stefan-Boltzmann constant, Stefan's law, for blackbody radiation, Stegmaier, W, Steiner and Taborek correlation, for forced convective boiling, Stephan and Korner correlation, for boiling of binary mixtures, Stiffeners, PD5500 code guidelines for, Stiffeners, against external pressure, EN13445 guidance on, Stirred beds, heat transfer to, Stirred reactor model, for furnaces, Stone's strongly implicit method, Straight fins (longitudinal fins): Stratified gas-liquid flow: Stratified liquid-liquid-gas flow: Steam analysis methods, for shell-side heat transfer and pressure drop in shell-and-tube heat exchangers, Stress, compressive, in heat exchanger tubes, Stress corrosion cracking, of stainless steels, Stress equation models, for turbulent boundary layers, Stress-strain curve, for solids, Stress tensor: Stresses: Strip baffles, in tube bundles with longitudinal flow, Strouhal number, Subchannel analysis, for critical heat flux in rod bundles, Subcooled boiling: Subcooling: Sublayer, viscous, Submerged combustion, Successive over-under relaxation method for solution of implicit equations, Suction: Suction line exchangers in refrigeration, Sulfur: Sulfur compounds (organic): Sulfur dioxide: Sulfur hexafluoride: Sulfur trioxide: Supercritical fluids: Superficial velocity, in multiphase flow, Superheated gases: Superheated liquid, in metastable state, Superheated vapor, condensation of, on vertical surface, Supersaturation, as cause of fogging in condensers: Suppression of nucleate boiling, Surface catalysis, in augmentation of heat transfer, Surface condensers, Surface finish: Surface, hydraulically smooth, Surface material, effect on fouling, Surface models, in radiative heat transfer, Surface modification for drag reduction, Surface temperature, effect on fouling, Surface tension: Surfactants, in drag reduction, Suspension, radiation interaction phenomena in, Sutherland formula, for viscosity variation with temperature, Sutterby fluid (non-Newtonian), free convective heat transfer to, Swirling flow, in augmentation of heat transfer, Synthetic heat transfer media, Synthetic mixture heat transfer media,
T U V W X Y Z

Critical Properties of Mixtures

DOI 10.1615/hedhme.a.000508

5.2 PROPERTIES OF MIXTURES OF FLUIDS
5.2.7. Critical properties of mixtures

A. Introduction

Corresponding slates methods are frequently used in the estimation of physical properties. Their use involves scaling factors which, in the case of mixtures, are referred to as pseudocritical properties. These characterising constants are usually obtained through a process of averaging the constants of the pure constituent components. The averaging equations, or mixing rules, are essentially empirical in nature.

It is important to distinguish the pseudocritical constants of mixtures from their true critical points. The pseudocritical properties, which may differ substantially from the true critical properties, are only of interest when corresponding states correlations arce used to estimate physical properties of mixtures. True critical points of mixtures, on the other hand, have a physical meaning and then knowledge is essential for the investigation of the phase behaviour of mixtures and the identification of the various regions of their thermodynamic surfaces.

B. Pseudocritical constants

In applying the corresponding states principle to mixtures, it is assumed that the properties of a mixture will be the same as those of a pseudo-component whose critical temperature and pressure are equal to the pseudocritical properties of the mixture.

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