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E-type shells in shell-and-tube heat exchangers: Ebert and Panchal equation, for crude oil fouling, Eckert number, Eddy viscosity: Eddy diffusivity, of heat, Edge, D, Edwards, D K EEC code for thermal design of heat exchangers, Effective diffusivity, Effective thermal conductivity of fixed beds, Effective tube length in shell-and-tube heat exchangers, Effectiveness of a heat exchanger: Efficiency of fins, Eicosane: Eicosene: Ejectors, in flash distillation plant, EJMA (Expansion Joint Manufacturers Association), standards for expansion bellows Elastic properties of solids: El-Dessouky, H, Electrical enhancement processes, in heat transfer augmentation, Electric fields, effect on properties of rheologically complex materials, Electric fields, in augmentation of condensation, Electrical process heater, specification of, Electrokinetics, for heat transfer augmentation in microfluidic systems, Electromagnetic theory of radiation, Electrostatic fields in augmentation of heat transfer, Elements: Elhadidy relation between heat and momentum transfer, Embedding methods for radiative heat transfer in nonisothermal gases, Embittlement, of stainless steels, Emission of thermal radiation, in solids, Emissivity: Emitting media, interaction phenomena with, Emulsions, viscosity of, EN13445 (European Pressure Vessel Codes), design of heat exchangers to, Enclosures: Energy equation: Energy recovery, maximum, in heat exchanger network design, Enhanced surfaces, fouling in, Enhancement devices: Enlargements in pipes: Enthalpy: Entrainment in annular gas-liquid flow Entrance effects in heat and mass transfer: Entrance lengths, hydrodynamic in pipe flow, Entrance losses for tube inlet in shell-and-tube heat exchanger, Entry losses in plate heat exchangers, Entropy generation and minimisation Environmental impact, of fouling, Eotvos number: Epstein, N, Epstein matrix, for fouling, Equalizing rings, for expansion bellows, Equilibrium interphase: Equilibrium vapor nucleus, Equivalent sand roughness, Ergun equation, for pressure drop in fixed beds ESDU correlations: Esters: Ethane: Ethanol: Ethers: Ethyl acetate: Ethylacetylene: Ethylacrylate: Ethylamine: Ethylbenzene: Ethyl benzoate: Ethyl butanoate: Ethylcyclohexane: Ethylcyclopentane: Ethyl formate: Ethylene: Ethylene diamine: Ethylene glycol: Ethylene oxide: Ethylmercaptan: 1-Ethylnaphthalene: 2-Ethylnaphthalene: Ethyl proprionate: Ethyl propylether: Ettouney, H, Euler number: Eutectic mixtures, condensation of forming immiscible liquids, Evaporation: Evaporative crystallisers, Evaporators: Exergy, definition of, Exergy analysis, Exit losses for tubes in shell-and-tube exchanger, Expansion bellows, for shell-and-tube heat exchangers: EJMA (Expansion Joint Manufacturers Association), standards for Expansion joints, mechanical design of: Expansion of tubes into tube sheets: Expansion turbine, lost work in, Explosively clad plate, Explosive welding of tubes into tube sheets Explosive expansion joints, Extended surfaces (see also Fins) Externally induced convection, in kettle reboilers, Extinction coefficient, Extinction efficiency, Eyring fluid (non-Newtonian),

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HEDH
A B C D E
E-type shells in shell-and-tube heat exchangers: Ebert and Panchal equation, for crude oil fouling, Eckert number, Eddy viscosity: Eddy diffusivity, of heat, Edge, D, Edwards, D K EEC code for thermal design of heat exchangers, Effective diffusivity, Effective thermal conductivity of fixed beds, Effective tube length in shell-and-tube heat exchangers, Effectiveness of a heat exchanger: Efficiency of fins, Eicosane: Eicosene: Ejectors, in flash distillation plant, EJMA (Expansion Joint Manufacturers Association), standards for expansion bellows Elastic properties of solids: El-Dessouky, H, Electrical enhancement processes, in heat transfer augmentation, Electric fields, effect on properties of rheologically complex materials, Electric fields, in augmentation of condensation, Electrical process heater, specification of, Electrokinetics, for heat transfer augmentation in microfluidic systems, Electromagnetic theory of radiation, Electrostatic fields in augmentation of heat transfer, Elements: Elhadidy relation between heat and momentum transfer, Embedding methods for radiative heat transfer in nonisothermal gases, Embittlement, of stainless steels, Emission of thermal radiation, in solids, Emissivity: Emitting media, interaction phenomena with, Emulsions, viscosity of, EN13445 (European Pressure Vessel Codes), design of heat exchangers to, Enclosures: Energy equation: Energy recovery, maximum, in heat exchanger network design, Enhanced surfaces, fouling in, Enhancement devices: Enlargements in pipes: Enthalpy: Entrainment in annular gas-liquid flow Entrance effects in heat and mass transfer: Entrance lengths, hydrodynamic in pipe flow, Entrance losses for tube inlet in shell-and-tube heat exchanger, Entry losses in plate heat exchangers, Entropy generation and minimisation Environmental impact, of fouling, Eotvos number: Epstein, N, Epstein matrix, for fouling, Equalizing rings, for expansion bellows, Equilibrium interphase: Equilibrium vapor nucleus, Equivalent sand roughness, Ergun equation, for pressure drop in fixed beds ESDU correlations: Esters: Ethane: Ethanol: Ethers: Ethyl acetate: Ethylacetylene: Ethylacrylate: Ethylamine: Ethylbenzene: Ethyl benzoate: Ethyl butanoate: Ethylcyclohexane: Ethylcyclopentane: Ethyl formate: Ethylene: Ethylene diamine: Ethylene glycol: Ethylene oxide: Ethylmercaptan: 1-Ethylnaphthalene: 2-Ethylnaphthalene: Ethyl proprionate: Ethyl propylether: Ettouney, H, Euler number: Eutectic mixtures, condensation of forming immiscible liquids, Evaporation: Evaporative crystallisers, Evaporators: Exergy, definition of, Exergy analysis, Exit losses for tubes in shell-and-tube exchanger, Expansion bellows, for shell-and-tube heat exchangers: EJMA (Expansion Joint Manufacturers Association), standards for Expansion joints, mechanical design of: Expansion of tubes into tube sheets: Expansion turbine, lost work in, Explosively clad plate, Explosive welding of tubes into tube sheets Explosive expansion joints, Extended surfaces (see also Fins) Externally induced convection, in kettle reboilers, Extinction coefficient, Extinction efficiency, Eyring fluid (non-Newtonian),
F G H I J K L M N O P Q R S T U V W X Y Z

Emissivity of Solids

DOI 10.1615/hedhme.a.000521

5.4 PROPERTIES OF SOLIDS
5.4.4 Emissivity of solids

A. General introduction

Within the limits of Planck’s quantum theory, any kind of energy input to an atom or molecule can cause one or more of its electrons to rise to a higher-energy state. In returning to a lower state the electron will emit a photon — the quantum of electromagnetic radiation — the energy of which is

\[\label{eq1} E_q=h\nu\;\;\;\;\mbox{J} \tag{1}\]

where h is Planck’s quantum constant = 6.62 × 10–34 J s and ν the frequency of the electromagnetic wave in s–1.

As long as only single atoms are considered there are a limited number of discrete states of energy, the differences of which correspond with the frequencies of the photons that can be emitted or absorbed. These frequencies or spectral lines are characteristic for the kind of atom in question.

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