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McNaught, J M,
Macdonald equation, for fixed-bed pressure drop,
Mach number,
Macleod-Sugden method for surface tension
Macrolayer consumption model for critical heat flux in pool boiling,
Maddox, R N
Magnetic fields, effect on properties of rheologically complex materials,
Magnetic devices, for fouling mitigation,
Magnetohydrodynamcs, inaugmentation of heat transfer in microfluidic systems,
Margarine manufacture, crystallization of edible oils and fats in, scraped surface heat exchangers for,
Marlotherm, heat transfer media,
Martensitic stainless steels,
Martin, H
Martinelli and Boelter equations for combined free and forced convection,
Martinelli and Nelson correlations:
Mass absorption coefficient,
Mass extinction coefficient,
Mass fraction, in multicomponent mixtures,
Mass scattering coefficient,
Mass transfer:
Mass transfer coefficient:
Materials of construction, for heat exchangers,
Low temperature operation, ASME VIII code guidelines for,
Matovosian, Robert,
Matrix inversion techniques, in radiative heat transfer,
Maximum drag reduction
Maximum velocities (in shell-and-tube heat exchangers)
Maxwell model, for non-Newtonian fluid,
Maxwell-Stefan equations, for multicomponent diffusion,
Maxwell's equations, for electromagnetic radiation,
Mean beam length concept, in radiative heat transfer:
Mean phase content,
Mean temperature difference:
Measurement of fouling resistance,
Mechanical design of heat exchangers:
Mechanical draft cooling towers,
Mechanical loads, specifications in EN13445,
Mechanical vapour compression cycles in refrigeration,
Mediatherm, heat transfer medium,
Melo, L F,
Melting, thermal conduction in,
Melting point:
Mercury:
Merilo correlation, for critical heat flux in horizontal tubes,
Merkel's equation, in cooling tower design,
Mertz, R,
Metais and Eckert diagrams, for regimes of convection:
Metals:
Metallurgical industry, kilns and furnaces for,
Metastable equilibrium, of vapor and liquid,
Methane:
Methanol:
Methyl acetate:
Methylacetylene:
Methyl acrylate:
Methyl amine
n-Methylaniline:
Methyl benzoate:
2-Methyl-1,3-Butadiene (Isoprene):
2-Methylbutane (isopentane):
Methylbutanoate:
2-Methyl-2-butene:
Methylcyclohexane:
Methylcyclopentane:
Methylethylketone:
Methyl formate:
Metallurgical slag, use of submerged combustion in reprocessing of,
Methyl fluorate:
2-Methylhexane:
Methylisobutylketone:
Methylmercaptan:
1-Methylnaphthalene:
2-Methylnaphthalene:
2-Methylpentane:
3-Methylpentane:
2-Methylpropane (isobutane):
2-Methylpropene:
Methyl propionate:
Methylpropylether:
Methylpropyl ketone:
Methyl salicylate:
Methyl-t-butyl ether:
Microbubbles, for drag reduction,
Microchannels (see also microfluidics)
Micro-fin tubes:
Microfluidics, enhancement of heat transfer in,
Mie scattering, in pulverized coal combustion,
Miller, C J
Miller, E R
Mineral oils, as heat transfer media, physical properties of,
Mineral wool production, submerged combustion systems for,
Minimum fluidization velocity,
Minimum heat flux in pool boiling:
Minimum tubeside velocity, in shell-and-tube heat exchangers,
Minimum velocity for fluidization,
Minimum wetting rate, for binary mixtures,
Mirror-image concept, in radiative heat transfer,
Mirrors, spectral characteristics of reflectance from,
Mishkinis, D,
Mist flow:
Mitigation of fouling,
Mixed convection occurrence in horiozntal circular pipe, Metais and Eckert diagram for,
Mixing (shell-side), in twisted tube heat exchangers,
Mixing length, in turbulent flow,
Mixtures:
Modelling, of fouling:
Models, theory of,
Modulus of elasticity:
Moffat, R S M,
Molecular gas radiation properties,
Molecular weight:
Mollier chart, for humid air,
Momentum equation:
Monitoring, on line, of fouling,
Monochloroacetic acid:
Monte Carlo methods, in radiative heat transfer,
Moody chart:
Morris, M
Mostinski correlations:
Moving bed, heat transfer to,
Muchowski, E,
Mueller, A C
Muller-Steinhagen, H
Multicomponent mixtures:
boiling of, in kettle reboilers,
boiling of, in evaporators,
condensation of
forced convective boiling of,
of gases, radiation properties of,
phase equilibria in,
physical properties,
pool boiling,
Multidimensional systems, heat conduction in,
Multiflux methods, for radiative heat transfer in nonisothermal gases,
Multipass shell-and-tube heat exchangers,
Multiphase fluid flow and pressure drop:
Multiple duties, in plate heat exchangers,
Multiple effect evaporation,
Multiple hairpin heat exchanger,
Multistage flash evaporation (MSF)
Multizone model, for furnaces,
Index
HEDH
A
B
C
D
E
F
G
H
I
J
K
L
M
McNaught, J M,
Macdonald equation, for fixed-bed pressure drop,
Mach number,
Macleod-Sugden method for surface tension
Macrolayer consumption model for critical heat flux in pool boiling,
Maddox, R N
Magnetic fields, effect on properties of rheologically complex materials,
Magnetic devices, for fouling mitigation,
Magnetohydrodynamcs, inaugmentation of heat transfer in microfluidic systems,
Margarine manufacture, crystallization of edible oils and fats in, scraped surface heat exchangers for,
Marlotherm, heat transfer media,
Martensitic stainless steels,
Martin, H
Martinelli and Boelter equations for combined free and forced convection,
Martinelli and Nelson correlations:
Mass absorption coefficient,
Mass extinction coefficient,
Mass fraction, in multicomponent mixtures,
Mass scattering coefficient,
Mass transfer:
Mass transfer coefficient:
Materials of construction, for heat exchangers,
Low temperature operation, ASME VIII code guidelines for,
Matovosian, Robert,
Matrix inversion techniques, in radiative heat transfer,
Maximum drag reduction
Maximum velocities (in shell-and-tube heat exchangers)
Maxwell model, for non-Newtonian fluid,
Maxwell-Stefan equations, for multicomponent diffusion,
Maxwell's equations, for electromagnetic radiation,
Mean beam length concept, in radiative heat transfer:
Mean phase content,
Mean temperature difference:
Measurement of fouling resistance,
Mechanical design of heat exchangers:
Mechanical draft cooling towers,
Mechanical loads, specifications in EN13445,
Mechanical vapour compression cycles in refrigeration,
Mediatherm, heat transfer medium,
Melo, L F,
Melting, thermal conduction in,
Melting point:
Mercury:
Merilo correlation, for critical heat flux in horizontal tubes,
Merkel's equation, in cooling tower design,
Mertz, R,
Metais and Eckert diagrams, for regimes of convection:
Metals:
Metallurgical industry, kilns and furnaces for,
Metastable equilibrium, of vapor and liquid,
Methane:
Methanol:
Methyl acetate:
Methylacetylene:
Methyl acrylate:
Methyl amine
n-Methylaniline:
Methyl benzoate:
2-Methyl-1,3-Butadiene (Isoprene):
2-Methylbutane (isopentane):
Methylbutanoate:
2-Methyl-2-butene:
Methylcyclohexane:
Methylcyclopentane:
Methylethylketone:
Methyl formate:
Metallurgical slag, use of submerged combustion in reprocessing of,
Methyl fluorate:
2-Methylhexane:
Methylisobutylketone:
Methylmercaptan:
1-Methylnaphthalene:
2-Methylnaphthalene:
2-Methylpentane:
3-Methylpentane:
2-Methylpropane (isobutane):
2-Methylpropene:
Methyl propionate:
Methylpropylether:
Methylpropyl ketone:
Methyl salicylate:
Methyl-t-butyl ether:
Microbubbles, for drag reduction,
Microchannels (see also microfluidics)
Micro-fin tubes:
Microfluidics, enhancement of heat transfer in,
Mie scattering, in pulverized coal combustion,
Miller, C J
Miller, E R
Mineral oils, as heat transfer media, physical properties of,
Mineral wool production, submerged combustion systems for,
Minimum fluidization velocity,
Minimum heat flux in pool boiling:
Minimum tubeside velocity, in shell-and-tube heat exchangers,
Minimum velocity for fluidization,
Minimum wetting rate, for binary mixtures,
Mirror-image concept, in radiative heat transfer,
Mirrors, spectral characteristics of reflectance from,
Mishkinis, D,
Mist flow:
Mitigation of fouling,
Mixed convection occurrence in horiozntal circular pipe, Metais and Eckert diagram for,
Mixing (shell-side), in twisted tube heat exchangers,
Mixing length, in turbulent flow,
Mixtures:
Modelling, of fouling:
Models, theory of,
Modulus of elasticity:
Moffat, R S M,
Molecular gas radiation properties,
Molecular weight:
Mollier chart, for humid air,
Momentum equation:
Monitoring, on line, of fouling,
Monochloroacetic acid:
Monte Carlo methods, in radiative heat transfer,
Moody chart:
Morris, M
Mostinski correlations:
Moving bed, heat transfer to,
Muchowski, E,
Mueller, A C
Muller-Steinhagen, H
Multicomponent mixtures:
N
O
P
Q
R
S
T
U
V
W
X
Y
Z
boiling of, in kettle reboilers,
boiling of, in evaporators,
condensation of
forced convective boiling of,
of gases, radiation properties of,
phase equilibria in,
physical properties,
pool boiling,
Multidimensional systems, heat conduction in,
Multiflux methods, for radiative heat transfer in nonisothermal gases,
Multipass shell-and-tube heat exchangers,
Multiphase fluid flow and pressure drop:
Multiple duties, in plate heat exchangers,
Multiple effect evaporation,
Multiple hairpin heat exchanger,
Multistage flash evaporation (MSF)
Multizone model, for furnaces,
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Boiling of Binary and Multicomponent Mixture: Basic Processes
DOI 10.1615/hedhme.a.000196
2.7 BOILING AND EVAPORATION
2.7.6 Boiling of binary and multicomponent mixtures: Basic processes
J. G. Collier and G. F. Hewitt
Section 191, Section 192, Section 193, Section 194 and Section 195 discuss the behavior of pure single-component fluids during evaporation. However, in the chemical and petroleum industries in particular, many processes involve the evaporation (and condensation) of binary (n = 2) and multicomponent (n > 2) mixtures, where n is the number of components. There are thermodynamic advantages, also, in using mixtures of refrigerants which evaporate and condense over a range of temperatures. In the boiling of binary and multicomponent mixtures, the heat transfer and the mass transfer processes are closely linked, with the evaporation rate often being limited by the mass transfer processes. This is significantly different from single-component systems, where interfacial mass transfer rates are normally very high.
In this section the differences to be expected in the basic physical processes will be considered. This will lead to a presentation of the available information on pool boiling of mixtures (Section 197). Finally, the problems of predicting heat transfer rates in forced convective evaporation of mixtures will be examined (Section 198). Starting with the early work of Bonilla and Perry (1941) and Cichelli and Bonilla (1944), a considerable body of published information on pool boiling of biliary mixtures has been built up. There is less information on forced convective evaporation though recent work has revealed some surprising features.
A. Elementary phase equilibrium
(a) Binary systems
If we consider a mixture of vapours consisting of components A and B which has a total pressure p then we can regard this pressure as being made up of partial pressures pA and pB such that p = pA + pB. Strictly speaking, the concept of partial pressure applies only to ideal vapour mixtures where the partial pressure pi, related to the mole fraction ỹi, of the ith component in the mixture. Thus:
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