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Packaged units, specification of,
Packing characteristic, in cooling towers,
Packings, for cooling towers
Packings, for fixed beds:
Packinox heat exchanger,
Paints, spectral characteristics of reflectance of surfaces treated with,
Palen, J W
Panchal, C B,
Paraffins, normal and isonormal:
Paraldehyde:
Parallel channel instability, in condensers,
Partial boiling in subcooled forced convective heat transfer,
Participating media, radiation interaction in,
Particle convective component, in heat transfer from fluidized beds,
Particle emissivity,
Particle Reynolds number in fixed beds,
Particles:
Particulate fluidization,
Particulate fouling,
Pass arrangements, in plate heat exchangers,
Passes, tube side,
Passive methods, for augmentation of heat transfer, passive systems for:
PD5500 mechanical design of shell-and-tube heat exchangers to,
Peacock, D K,
Pearson number,
Peclet number
Peng-Robinson equation of state, application to hydrocarbons,
Penner's rule, in absorption of radiation by gases,
Pentachloroethane (Refrigerant 120):
Pentadecane:
Pentadecene:
Pentadiene 1, 2:
Pentadiene 1, trans 3:
Pentadiene 1, 4:
Pentadiene 2-3:
Pentafluoroethane (Refrigerant 125)
Pentamethylbenzene:
Pentane:
Pentanoic acid:
1-Pentanol:
1-Pentene:
cis-2-Pentene:
trans-2-Pentene:
Pentylacetate:
Pentylbenzene:
Pentylcyclohexane:
Pentylcyclopentane:
Pentylcyclopropane, liquid properties,
Perforated fins, in plate fin heat exchangers,
Perforated plates, loss coefficients in,
Periodic operation, of regenerator,
Periodic variations in temperature, thermal conduction in bodies with,
PFR correlation, for heat transfer in high fin tube banks,
Pharmaceutical industry, fouling of heat exchangers in,
Phase change materials, in augmentation of heat transfer,
Phase change number,
Phase equilibrium:
Phase inversion
Phase separation, as source of corrosion problems,
Phenol:
Phenols:
Phenylhydrazine:
Phonons, in thermal conductivity of solids,
Phosgene:
Physical properties:
Pi theorum, in dimensional analysis,
Pinch analysis, for heat exchanger network design,
Pioro, I L
Pioro, LS,
Pipe leads,
Piperidine:
Pipes, circular:
Pipes, noncircular:
Piping components:
Pitting corrosion, in stainless steels,
Planck's constant,
Planck's law, for spectral distribution of blackbody radiation,
Plane shells, steady-state thermal conduction in,
Plastic deformation
Plate fin heat exchangers
Plate fins, efficiency,
Plate heat exchangers:
Plate evaporator
Plates:
Plug flow:
Plug flow model, for furnaces,
Pneumatic conveyance,
Pneumatic conveying dryer,
P-NTU method:
Polarization, of thermal radiation,
Polyglycols, as heat transfer media,
Polymers:
Pool boiling,
Porous surfaces:
Port arrangements, in plate heat exchangers,
Portable fouling unit,
Poskas, P,
Postdryout heat transfer:
Powders:
Power law fluid (non-Newtonian),
Power plant:
Prandtl number
Precipitation (crystallization) fouling,
Precipitation hardening, of stainless steels,
Pressure coefficient:
Pressure control of condensers,
Pressure drop:
Pressure gradient:
Pressure, specification of in mechanical design to EN13445,
Pressure testing,
Pressure vessels, principle codes for,
Pressurised water reactor, fouling in,
Printed circuit heat exchanger,
Problem table algorithm, in pinch analysis,
Process heaters:
Progressive plastic deformation
Prolate spheroids, free convective heat transfer from,
Promoters, in dropwise condensation,
Propadiene:
Propane:
1-Propanol:
2-Propanol:
Propeller agitator,
Property ratio method, for temperature dependent physical property
Propionaldehyde:
Propionic acid:
Propionic anhydride:
Proprionitrile:
Propyl acetate:
Propylamine:
Propylbenzene:
Propylcyclohexane:
Propylcyclopentane:
Propylene:
1,3-Propylene glycol:
Propylene oxide:
Propyl formate:
Propyl propionate:
Pseudo-boiling in supercritical fluids,
Pseudo-film boiling in supercritical fluids,
Pseudocritical pressure,
Pseudocritical tempertaure,
Pugh, S F
Pulp and paper industry, fouling of heat exchangers in,
Pulsations, use in augmentation of heat transfer,
Pulverized fuel water-tube boiler,
Pumping, lost work in,
Pushkina and Sorokin correlation, for flooding in vertical tubes,
Pyramid, free convective heat transfer from,
Pyridine:
Index
HEDH
A
B
C
D
E
F
G
H
I
J
K
L
M
N
O
P
Packaged units, specification of,
Packing characteristic, in cooling towers,
Packings, for cooling towers
Packings, for fixed beds:
Packinox heat exchanger,
Paints, spectral characteristics of reflectance of surfaces treated with,
Palen, J W
Panchal, C B,
Paraffins, normal and isonormal:
Paraldehyde:
Parallel channel instability, in condensers,
Partial boiling in subcooled forced convective heat transfer,
Participating media, radiation interaction in,
Particle convective component, in heat transfer from fluidized beds,
Particle emissivity,
Particle Reynolds number in fixed beds,
Particles:
Particulate fluidization,
Particulate fouling,
Pass arrangements, in plate heat exchangers,
Passes, tube side,
Passive methods, for augmentation of heat transfer, passive systems for:
PD5500 mechanical design of shell-and-tube heat exchangers to,
Peacock, D K,
Pearson number,
Peclet number
Peng-Robinson equation of state, application to hydrocarbons,
Penner's rule, in absorption of radiation by gases,
Pentachloroethane (Refrigerant 120):
Pentadecane:
Pentadecene:
Pentadiene 1, 2:
Pentadiene 1, trans 3:
Pentadiene 1, 4:
Pentadiene 2-3:
Pentafluoroethane (Refrigerant 125)
Pentamethylbenzene:
Pentane:
Pentanoic acid:
1-Pentanol:
1-Pentene:
cis-2-Pentene:
trans-2-Pentene:
Pentylacetate:
Pentylbenzene:
Pentylcyclohexane:
Pentylcyclopentane:
Pentylcyclopropane, liquid properties,
Perforated fins, in plate fin heat exchangers,
Perforated plates, loss coefficients in,
Periodic operation, of regenerator,
Periodic variations in temperature, thermal conduction in bodies with,
PFR correlation, for heat transfer in high fin tube banks,
Pharmaceutical industry, fouling of heat exchangers in,
Phase change materials, in augmentation of heat transfer,
Phase change number,
Phase equilibrium:
Phase inversion
Phase separation, as source of corrosion problems,
Phenol:
Phenols:
Phenylhydrazine:
Phonons, in thermal conductivity of solids,
Phosgene:
Physical properties:
Pi theorum, in dimensional analysis,
Pinch analysis, for heat exchanger network design,
Pioro, I L
Pioro, LS,
Pipe leads,
Piperidine:
Pipes, circular:
Pipes, noncircular:
Piping components:
Pitting corrosion, in stainless steels,
Planck's constant,
Planck's law, for spectral distribution of blackbody radiation,
Plane shells, steady-state thermal conduction in,
Plastic deformation
Plate fin heat exchangers
Plate fins, efficiency,
Plate heat exchangers:
Plate evaporator
Plates:
Plug flow:
Plug flow model, for furnaces,
Pneumatic conveyance,
Pneumatic conveying dryer,
P-NTU method:
Polarization, of thermal radiation,
Polyglycols, as heat transfer media,
Polymers:
Pool boiling,
Porous surfaces:
Port arrangements, in plate heat exchangers,
Portable fouling unit,
Poskas, P,
Postdryout heat transfer:
Powders:
Power law fluid (non-Newtonian),
Power plant:
Prandtl number
Precipitation (crystallization) fouling,
Precipitation hardening, of stainless steels,
Pressure coefficient:
Pressure control of condensers,
Pressure drop:
Pressure gradient:
Pressure, specification of in mechanical design to EN13445,
Pressure testing,
Pressure vessels, principle codes for,
Pressurised water reactor, fouling in,
Printed circuit heat exchanger,
Problem table algorithm, in pinch analysis,
Process heaters:
Progressive plastic deformation
Prolate spheroids, free convective heat transfer from,
Promoters, in dropwise condensation,
Propadiene:
Propane:
1-Propanol:
2-Propanol:
Propeller agitator,
Property ratio method, for temperature dependent physical property
Propionaldehyde:
Propionic acid:
Propionic anhydride:
Proprionitrile:
Propyl acetate:
Propylamine:
Propylbenzene:
Propylcyclohexane:
Propylcyclopentane:
Propylene:
1,3-Propylene glycol:
Propylene oxide:
Propyl formate:
Propyl propionate:
Pseudo-boiling in supercritical fluids,
Pseudo-film boiling in supercritical fluids,
Pseudocritical pressure,
Pseudocritical tempertaure,
Pugh, S F
Pulp and paper industry, fouling of heat exchangers in,
Pulsations, use in augmentation of heat transfer,
Pulverized fuel water-tube boiler,
Pumping, lost work in,
Pushkina and Sorokin correlation, for flooding in vertical tubes,
Pyramid, free convective heat transfer from,
Pyridine:
Q
R
S
T
U
V
W
X
Y
Z
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Boiling of Binary and Multicomponent Mixture: Basic Processes
DOI 10.1615/hedhme.a.000196
2.7 BOILING AND EVAPORATION
2.7.6 Boiling of binary and multicomponent mixtures: Basic processes
J. G. Collier and G. F. Hewitt
Section 191, Section 192, Section 193, Section 194 and Section 195 discuss the behavior of pure single-component fluids during evaporation. However, in the chemical and petroleum industries in particular, many processes involve the evaporation (and condensation) of binary (n = 2) and multicomponent (n > 2) mixtures, where n is the number of components. There are thermodynamic advantages, also, in using mixtures of refrigerants which evaporate and condense over a range of temperatures. In the boiling of binary and multicomponent mixtures, the heat transfer and the mass transfer processes are closely linked, with the evaporation rate often being limited by the mass transfer processes. This is significantly different from single-component systems, where interfacial mass transfer rates are normally very high.
In this section the differences to be expected in the basic physical processes will be considered. This will lead to a presentation of the available information on pool boiling of mixtures (Section 197). Finally, the problems of predicting heat transfer rates in forced convective evaporation of mixtures will be examined (Section 198). Starting with the early work of Bonilla and Perry (1941) and Cichelli and Bonilla (1944), a considerable body of published information on pool boiling of biliary mixtures has been built up. There is less information on forced convective evaporation though recent work has revealed some surprising features.
A. Elementary phase equilibrium
(a) Binary systems
If we consider a mixture of vapours consisting of components A and B which has a total pressure p then we can regard this pressure as being made up of partial pressures pA and pB such that p = pA + pB. Strictly speaking, the concept of partial pressure applies only to ideal vapour mixtures where the partial pressure pi, related to the mole fraction ỹi, of the ith component in the mixture. Thus:
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